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      Control of triboelectric charges on common polymers by photoexcitation of organic dyes

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          Abstract

          Triboelectric charging of insulators, also known as contact charging in which electrical charges develop on surfaces upon contact, is a significant problem that is especially critical for various industries such as polymers, pharmaceuticals, electronics, and space. Several methods of tribocharge mitigation exist in practice; however, none can reach the practicality of using light in the process. Here we show a light-controlled manipulation of triboelectric charges on common polymers, in which the tribocharges are mitigated upon illumination with appropriate wavelengths of light in presence of a mediator organic dye. Our method provides spatial and temporal control of mitigation of static charges on common polymer surfaces by a mechanism that involves photoexcitation of organic dyes, which also allows additional control using wavelength. This control over charge mitigation provides a way to manipulate macroscopic objects by tribocharging followed by light-controlled discharging.

          Abstract

          Contact charging of insulators is a significant problem for various industries, such as plastics, electronics, and space. Here the authors gain spatial and temporal control of discharge of triboelectrically charged polymers upon illumination of a set of common organic dyes.

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          Mechanochemistry: the mechanical activation of covalent bonds.

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            The mosaic of surface charge in contact electrification.

            When dielectric materials are brought into contact and then separated, they develop static electricity. For centuries, it has been assumed that such contact charging derives from the spatially homogeneous material properties (along the material's surface) and that within a given pair of materials, one charges uniformly positively and the other negatively. We demonstrate that this picture of contact charging is incorrect. Whereas each contact-electrified piece develops a net charge of either positive or negative polarity, each surface supports a random "mosaic" of oppositely charged regions of nanoscopic dimensions. These mosaics of surface charge have the same topological characteristics for different types of electrified dielectrics and accommodate significantly more charge per unit area than previously thought.
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              Contact electrification

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                Author and article information

                Contributors
                b-baytekin@fen.bilkent.edu.tr
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                17 January 2019
                17 January 2019
                2019
                : 10
                : 276
                Affiliations
                [1 ]ISNI 0000 0001 0723 2427, GRID grid.18376.3b, Department of Chemistry, , Bilkent University, ; 06800 Ankara, Turkey
                [2 ]ISNI 0000 0001 2169 7132, GRID grid.25769.3f, Department of Chemistry, Faculty of Science, , Gazi University, ; 06500 Teknikokullar, Ankara, Turkey
                [3 ]ISNI 0000 0001 0723 2427, GRID grid.18376.3b, UNAM-National Nanotechnology Research Center, , Bilkent University, ; 06800 Ankara, Turkey
                Author information
                http://orcid.org/0000-0002-3705-6601
                http://orcid.org/0000-0002-3867-3863
                Article
                8037
                10.1038/s41467-018-08037-5
                6336862
                30655528
                ab481613-1768-4c59-a61d-e00a08ae8f89
                © The Author(s) 2019

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 11 June 2018
                : 6 December 2018
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