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      Tribochemistry, Mechanical Alloying, Mechanochemistry: What is in a Name?

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          Abstract

          Over the decades, the application of mechanical force to influence chemical reactions has been called by various names: mechanochemistry, tribochemistry, mechanical alloying, to name but a few. The evolution of these terms has largely mirrored the understanding of the field. But what is meant by these terms, why have they evolved, and does it really matter how a process is called? Which parameters should be defined to describe unambiguously the experimental conditions such that others can reproduce the results, or to allow a meaningful comparison between processes explored under different conditions? Can the information on the process be encoded in a clear, concise, and self-explanatory way? We address these questions in this Opinion contribution, which we hope will spark timely and constructive discussion across the international mechanochemical community.

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          The FAIR Guiding Principles for scientific data management and stewardship

          There is an urgent need to improve the infrastructure supporting the reuse of scholarly data. A diverse set of stakeholders—representing academia, industry, funding agencies, and scholarly publishers—have come together to design and jointly endorse a concise and measureable set of principles that we refer to as the FAIR Data Principles. The intent is that these may act as a guideline for those wishing to enhance the reusability of their data holdings. Distinct from peer initiatives that focus on the human scholar, the FAIR Principles put specific emphasis on enhancing the ability of machines to automatically find and use the data, in addition to supporting its reuse by individuals. This Comment is the first formal publication of the FAIR Principles, and includes the rationale behind them, and some exemplar implementations in the community.
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            Mechanochemistry: opportunities for new and cleaner synthesis.

            The aim of this critical review is to provide a broad but digestible overview of mechanochemical synthesis, i.e. reactions conducted by grinding solid reactants together with no or minimal solvent. Although mechanochemistry has historically been a sideline approach to synthesis it may soon move into the mainstream because it is increasingly apparent that it can be practical, and even advantageous, and because of the opportunities it provides for developing more sustainable methods. Concentrating on recent advances, this article covers industrial aspects, inorganic materials, organic synthesis, cocrystallisation, pharmaceutical aspects, metal complexes (including metal-organic frameworks), supramolecular aspects and characterization methods. The historical development, mechanistic aspects, limitations and opportunities are also discussed (314 references). This journal is © The Royal Society of Chemistry 2012
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              Definition of the halogen bond (IUPAC Recommendations 2013)

              This recommendation proposes a definition for the term “halogen bond”, which designates a specific subset of the inter- and intramolecular interactions involving a halogen atom in a molecular entity.
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                Author and article information

                Contributors
                Journal
                Front Chem
                Front Chem
                Front. Chem.
                Frontiers in Chemistry
                Frontiers Media S.A.
                2296-2646
                26 May 2021
                2021
                : 9
                : 685789
                Affiliations
                [ 1 ]Federal Institute for Materials Research and Testing (BAM), Berlin, Germany
                [ 2 ]Novosibirsk State University, Novosibirsk, Russia
                [ 3 ]Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
                [ 4 ]Yusef Hamied Department of Chemistry, University of Cambridge, Cambridge, United Kingdom
                [ 5 ]Voevodski Institute of Chemical Kinetics and Combustion SB RAS, Novosibirsk, Russia
                Author notes

                Edited by: Lev S. Rapoport, Holon Institute of Technology, Israel

                Reviewed by: Kenneth John MacKenzie, MacDiarmid Institute for Advanced Materials and Nanotechnology, New Zealand

                Vladislav V. Gurzhiy, Saint Petersburg State University, Russia

                *Correspondence: Elena V. Boldyreva, eboldyreva@ 123456yahoo.com , eboldyreva@ 123456catalysis.ru ; Adam A. L. Michalchuk, adam.michalchuk@ 123456bam.de

                This article was submitted to Solid State Chemistry, a section of the journal Frontiers in Chemistry

                Article
                685789
                10.3389/fchem.2021.685789
                8216082
                34164379
                7d74cd1e-2c15-470e-b835-ff4f2290b16b
                Copyright © 2021 Michalchuk, Boldyreva, Belenguer, Emmerling and Boldyrev.

                This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

                History
                : 25 March 2021
                : 03 May 2021
                Funding
                Funded by: Russian Science Support Foundation 10.13039/100009409
                Categories
                Chemistry
                Review

                mechanochemistry,tribochemistry,mechanical alloying,tribology,mechanical activation,nomenclature,mechanochemical pictographs

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