Interplay between Lattice Distortion and Spin-Orbit Coupling in Double Perovskites

Abstract

We develop anisotropic pseudo-spin antiferromagnetic Heisenberg models for monoclinically distorted double perovskites. We focus on these A\(_2\)BB'O\(_6\) materials that have magnetic moments on the 4d or 5d transition metal B' ions, which form a face-centered cubic lattice. In these models, we consider local z-axis distortion of B'-O octahedra, affecting relative occupancy of \(t_{2g}\) orbitals, along with geometric effects of the monoclinic distortion, and spin-orbit coupling. The resulting pseudo-spin-1/2 models are solved in the saddle-point limit of the Sp(N) generalization of the Heisenberg model. The spin S in the SU(2) case generalizes as a parameter \(\kappa\) controlling quantum fluctuation in the Sp(N) case. We consider two different models that may be appropriate for these systems. In particular, using Heisenberg exchange parameters for La\(_2\)LiMoO\(_6\) from a spin-dimer calculation, we conclude that this pseudo-spin-1/2 system may order, but must be very close to a disordered spin liquid state.