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Tuning the work-function via strong coupling.

Author(s): Cyriaque Genet, Andrea Liscio, Daniel Schwartz, Thomas Ebbesen, Christopher J Hutchison, A. Durand, Paolo Samorì, Vincenzo Palermo

Publication date: 2013-05-07

Journal: Advanced Materials (Deerfield Beach, Fla.)

Keywords: Electron Transport, Energy Transfer, Interferometry, methods, Materials Testing, Membranes, Artificial, Polymers, chemistry, Surface Plasmon Resonance

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Abstract

The tuning of the molecular material work-function via strong coupling with vacuum electromagnetic fields is demonstrated. Kelvin probe microscopy extracts the surface potential (SP) changes of a photochromic molecular film on plasmonic hole arrays and inside Fabry-Perot cavities. Modulating the optical cavity resonance or the photochromic film effectively tunes the work-function, suggesting a new tool for tailoring material properties. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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PubMed ID:: 23463588

DOI:: 10.1002/adma.201203682

ScienceOpen disciplines: Chemistry

Keywords: Electron Transport,Energy Transfer,Interferometry,methods,Materials Testing,Membranes, Artificial,Polymers,chemistry,Surface Plasmon Resonance

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ScienceOpen disciplines: Chemistry

Keywords: Electron Transport, Energy Transfer, Interferometry, methods, Materials Testing, Membranes, Artificial, Polymers, chemistry, Surface Plasmon Resonance

Tuning the work-function via strong coupling.

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