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      Functional Conducting Polymers via Thiol-ene Chemistry

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      Author(s): ,   *
      Publication date (Electronic):
      Journal: Biosensors
      Publisher: MDPI
      Keywords: conducting polymer, thiol-ene, ProDOT, functionalization

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          Abstract

          We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.

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          Plastic Solar Cells

          C. Brabec, N S Sariciftci, J Hummelen (2001)
          Article 0 comments Cited 626 times – based on 0 reviews     Review now
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            Robust, efficient, and orthogonal synthesis of dendrimers via thiol-ene "click" chemistry.

            Kato Killops, Luis Campos, Craig Hawker (2008)
            Dendrimers up to the fourth generation were successfully prepared via the divergent growth strategy using a combination of thiol-ene "click" chemistry and traditional esterification reactions. The thiol-ene reactions were conducted under solvent-free, ambient conditions at room temperature by irradiating with UV light. The fourth-generation dendrimers were subsequently functionalized with carboxylic acid, pyrene, and Fmoc-protected cysteine moieties via thiol-ene reactions.
            Article 0 comments Cited 164 times – based on 0 reviews     Review now
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              Controlling Interchain Interactions in Conjugated Polymers:  The Effects of Chain Morphology on Exciton−Exciton Annihilation and Aggregation in MEH−PPV Films

              Jei Liu, Thuc-Quyen Nguyen, Ignacio Martini … (2000)
              Article 0 comments Cited 120 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (nlm-ta): Biosensors (Basel)
                Journal ID (iso-abbrev): Biosensors (Basel)
                Journal ID (publisher-id): biosensors
                Title: Biosensors
                Publisher: MDPI
                ISSN (Electronic): 2079-6374
                Publication date (Electronic): 31 August 2012
                Publication date Collection: September 2012
                Volume: 2
                Issue: 3
                Pages: 305-317
                Affiliations
                Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA; E-Mail: katiefeldman0@ 123456gmail.com
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: milty@ 123456udel.edu ; Tel.: +1-302-831-2062; Fax: +1-508-256-8352.
                Article
                Publisher ID: biosensors-02-00305
                DOI: 10.3390/bios2030305
                PMC ID: 4263549
                SO-VID: f5983c0c-98f0-4616-b13a-d73459c72036
                Copyright © © 2012 by the authors; licensee MDPI, Basel, Switzerland.
                License:

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                Date received : 16 July 2012
                Date revision received : 16 August 2012
                Date accepted : 28 August 2012
                Categories
                Subject: Article

                Keywords: conducting polymer,thiol-ene,prodot,functionalization
                Data availability:
                Keywords: conducting polymer, thiol-ene, prodot, functionalization

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