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      Recent progress in synergistic catalysis over heterometallic nanoparticles

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      Journal of Materials Chemistry
      Royal Society of Chemistry (RSC)

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          Semiconductor Clusters, Nanocrystals, and Quantum Dots

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            High-performance electrocatalysts for oxygen reduction derived from polyaniline, iron, and cobalt.

            The prohibitive cost of platinum for catalyzing the cathodic oxygen reduction reaction (ORR) has hampered the widespread use of polymer electrolyte fuel cells. We describe a family of non-precious metal catalysts that approach the performance of platinum-based systems at a cost sustainable for high-power fuel cell applications, possibly including automotive power. The approach uses polyaniline as a precursor to a carbon-nitrogen template for high-temperature synthesis of catalysts incorporating iron and cobalt. The most active materials in the group catalyze the ORR at potentials within ~60 millivolts of that delivered by state-of-the-art carbon-supported platinum, combining their high activity with remarkable performance stability for non-precious metal catalysts (700 hours at a fuel cell voltage of 0.4 volts) as well as excellent four-electron selectivity (hydrogen peroxide yield <1.0%).
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              One-Dimensional Nanostructures: Synthesis, Characterization, and Applications

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                Author and article information

                Journal
                JMACEP
                Journal of Materials Chemistry
                J. Mater. Chem.
                Royal Society of Chemistry (RSC)
                0959-9428
                1364-5501
                2011
                2011
                : 21
                : 36
                : 13705
                Article
                10.1039/c1jm12020d
                ee925caf-5247-4b92-943c-11a1d53565cc
                © 2011
                History

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