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      Gamma Radiation Processed Polymeric Materials for High Performance Applications: A Review

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          Abstract

          The polymeric properties are tailored and enhanced by high energy radiation processing, which is an effective technique to tune the physical, chemical, thermal, surface, and structural properties of the various thermoplastic and elastomeric polymeric components. The gamma and electron beam radiation are the most frequent radiation techniques used for crosslinking, compatibilizing, and grafting of various polymer blends and composites systems. The gamma radiation-induced grafting and crosslinking are the effective, rapid, clean, user-friendly, and well-controlled techniques for the polymeric materials for their properties improvement for high performance applications such as nuclear, automobile, electrical insulation, ink curing, surface modification, food packaging, medical, sterilization, and health-care in a different environment. Similarly, electron beam radiations crosslinking has been a well-known technique for properties development and has economic benefits over chemical crosslinking techniques. This review focuses on the development of polymeric multi component systems (functionalized polymer, blends, and nanohybrids), where partially nanoscale clay incorporation can achieve the desired properties, and partially by controlled high energy radiations crosslinking of blends and nanocomposites. In this review, various investigations have been studied on the development and modifications of polymeric systems, and controlled dose gamma radiation processed the polymer blends and clay-induced composites. Radiation induced grafting of the various monomers on the polymer backbone has been focused. Similarly, comparative studies of gamma and electron beam radiation and their effect on property devlopment have been focused. The high energy radiation modified polymers have been used in several high performance sectors, including automotive, wire and cable insulation, heat shrinkable tube, sterilization, biomedical, nuclear and space applications.

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          Most cited references85

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          Grafting: a versatile means to modify polymersTechniques, factors and applications

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            Polymeric composite materials for radiation shielding: a review

            The rising use of radioactive elements is increasing radioactive pollution and calling for advanced materials to protect individuals. For instance, polymers are promising due to their mechanical, electrical, thermal, and multifunctional properties. Moreover, composites made of polymers and high atomic number fillers should allow to obtain material with low-weight, good flexibility, and good processability. Here we review the synthesis of polymer materials for radiation protection, with focus on the role of the nanofillers. We discuss the effectivness of polymeric materials for the absorption of fast neutrons. We also present the recycling of polymers into composites.
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              High-energy radiation and polymers: A review of commercial processes and emerging applications

              R.L Clough (2001)
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                Author and article information

                Contributors
                Journal
                Front Chem
                Front Chem
                Front. Chem.
                Frontiers in Chemistry
                Frontiers Media S.A.
                2296-2646
                14 March 2022
                2022
                : 10
                : 837111
                Affiliations
                [1] 1 Department of Polymer and Surface Engineering , Institute of Chemical Technology , Mumbai, India
                [2] 2 Department of Chemistry , Faculty of Science , MUIS, Ganpat University , Mehsana, India
                Author notes

                Edited by: Md. Abu Bin Hasan Susan, University of Dhaka, Bangladesh

                Reviewed by: Md. Sirajul Islam, University of New South Wales, Australia

                Kumkum Ahmed, Shibaura Institute of Technology, Japan

                *Correspondence: Prakash A. Mahanwar, pa.mahanwar@ 123456ictmumbai.edu.in ; Bhuwanesh Kumar Sharma, bks02@ 123456ganpatuniversity.ac.in
                [ † ]

                These authors have contributed equally to this work

                This article was submitted to Polymer Chemistry, a section of the journal Frontiers in Chemistry

                Article
                837111
                10.3389/fchem.2022.837111
                8964295
                35360545
                ea7142b8-2fd2-40b5-94e4-d5a71414ea04
                Copyright © 2022 Naikwadi, Sharma, Bhatt and Mahanwar.

                This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

                History
                : 16 December 2021
                : 31 January 2022
                Categories
                Chemistry
                Review

                gamma radiation induced grafting,gamma induced crosslinking,polymer modification,high performance applications,electron beam radiation

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