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      Metal nanoparticles loaded polyurethane nano-composites and their catalytic/antimicrobial applications: a critical review

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          Abstract

          Polyurethane (PU) belongs to a unique class of polymers. Different properties of PU such as mechanical strength and biocompatibility can be enhanced by co-polymerizing it with different bio and synthetic polymers. It finds huge applications as micro-reactors for the fabrication of metal nanoparticles (MNPs) owing to the synergistic properties of both polyurethane and fabricated metal nanoparticles. Metal nanoparticles fabricated polyurethane have gained much attention in the last few years. These types of nanocomposites hyphenate the mechanical properties of polyurethane with the high surface-to-volume ratio of metal nanoparticles. Here, this review article briefly evaluates different methods of synthesis of polyurethane-based metal nanocomposites and their characterization via different techniques to evaluate their properties. Applications of these polyurethane based nanocomposite materials have also been described critically in different fields depending upon their catalytic, antimicrobial and antifungal potential. Future directions of these nanocomposite materials have also been described in the field of designing of nano-filters and nano-devices in order to attain environmental remediation and sustainability.

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          Responsive Polymers for Detection and Sensing Applications: Current Status and Future Developments

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            Is Open Access

            Antimicrobial Polymers with Metal Nanoparticles

            Metals, such as copper and silver, can be extremely toxic to bacteria at exceptionally low concentrations. Because of this biocidal activity, metals have been widely used as antimicrobial agents in a multitude of applications related with agriculture, healthcare, and the industry in general. Unlike other antimicrobial agents, metals are stable under conditions currently found in the industry allowing their use as additives. Today these metal based additives are found as: particles, ions absorbed/exchanged in different carriers, salts, hybrid structures, etc. One recent route to further extend the antimicrobial applications of these metals is by their incorporation as nanoparticles into polymer matrices. These polymer/metal nanocomposites can be prepared by several routes such as in situ synthesis of the nanoparticle within a hydrogel or direct addition of the metal nanofiller into a thermoplastic matrix. The objective of the present review is to show examples of polymer/metal composites designed to have antimicrobial activities, with a special focus on copper and silver metal nanoparticles and their mechanisms.
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              In situ green synthesis of Ag nanoparticles on graphene oxide/TiO 2 nanocomposite and their catalytic activity for the reduction of 4-nitrophenol, congo red and methylene blue

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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                Reviews in Chemical Engineering
                Walter de Gruyter GmbH
                0167-8299
                2191-0235
                October 28 2024
                July 26 2024
                October 01 2024
                October 28 2024
                July 26 2024
                October 01 2024
                : 40
                : 7
                : 859-886
                Affiliations
                [1 ]Department of Basic and Applied Chemistry, Faculty of Science and Technology , University of Central Punjab , Lahore 54590 , Pakistan
                [2 ]Department of Physics, College of Science and Humanities in Al-Kharj , Prince Sattam bin Abdulaziz University , Al-Kharj 11942 , Saudi Arabia
                [3 ]Department of Biology, College of Science and Humanities in Al-Kharj , Prince Sattam bin Abdul Aziz University , Al-Kharj 11942 , Saudia Arabia
                [4 ]Department of Microbiology, Faculty of Science and Technology , University of Central Punjab , Lahore 54000 , Pakistan
                [5 ]The National Center for Environmental Compliance (NCEC) , Riyadh , Saudia Arabia
                Article
                10.1515/revce-2024-0006
                be43a96b-bdee-4816-bca0-ea9aa827033d
                © 2024
                History

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