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      Levelized cost of CO2 mitigation from hydrogen production routes

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          Abstract

          The levelized cost of carbon mitigation and proportional decarbonisation fraction ranges of hydrogen production technologies relative to steam methane reforming.

          Abstract

          Different technologies produce hydrogen with varying cost and carbon footprints over the entire resource supply chain and manufacturing steps. This paper examines the relative costs of carbon mitigation from a life cycle perspective for 12 different hydrogen production techniques using fossil fuels, nuclear energy and renewable sources by technology substitution. Production costs and life cycle emissions are parameterized and re-estimated from currently available assessments to produce robust ranges to describe uncertainties for each technology. Hydrogen production routes are then compared using a combination of metrics, levelized cost of carbon mitigation and the proportional decarbonization benchmarked against steam methane reforming, to provide a clearer picture of the relative merits of various hydrogen production pathways, the limitations of technologies and the research challenges that need to be addressed for cost-effective decarbonization pathways. The results show that there is a trade-off between the cost of mitigation and the proportion of decarbonization achieved. The most cost-effective methods of decarbonization still utilize fossil feedstocks due to their low cost of extraction and processing, but only offer moderate decarbonisation levels due to previous underestimations of supply chain emissions contributions. Methane pyrolysis may be the most cost-effective short-term abatement solution, but its emissions reduction performance is heavily dependent on managing supply chain emissions whilst cost effectiveness is governed by the price of solid carbon. Renewable electrolytic routes offer significantly higher emissions reductions, but production routes are more complex than those that utilise naturally-occurring energy-dense fuels and hydrogen costs are high at modest renewable energy capacity factors. Nuclear routes are highly cost-effective mitigation options, but could suffer from regionally varied perceptions of safety and concerns regarding proliferation and the available data lacks depth and transparency. Better-performing fossil-based hydrogen production technologies with lower decarbonization fractions will be required to minimise the total cost of decarbonization but may not be commensurate with ambitious climate targets.

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          Most cited references82

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          Review and evaluation of hydrogen production methods for better sustainability

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            An overview of advances in biomass gasification

            The article reviews diverse areas of conventional and advanced biomass gasification discussing their feasibility and sustainability vis-à-vis technological and socio-environmental impacts. Biomass gasification is a widely used thermochemical process for obtaining products with more value and potential applications than the raw material itself. Cutting-edge, innovative and economical gasification techniques with high efficiencies are a prerequisite for the development of this technology. This paper delivers an assessment on the fundamentals such as feedstock types, the impact of different operating parameters, tar formation and cracking, and modelling approaches for biomass gasification. Furthermore, the authors comparatively discuss various conventional mechanisms for gasification as well as recent advances in biomass gasification. Unique gasifiers along with multi-generation strategies are discussed as a means to promote this technology into alternative applications, which require higher flexibility and greater efficiency. A strategy to improve the feasibility and sustainability of biomass gasification is via technological advancement and the minimization of socio-environmental effects. This paper sheds light on diverse areas of biomass gasification as a potentially sustainable and environmentally friendly technology.
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              A comparative technoeconomic analysis of renewable hydrogen production using solar energy

              Solar H 2 production cost (\(kg −1 ) techno-economic landscape for photoelectrochemical (PEC) and photovoltaic-electrolysis (PV-E). References include conventional H 2 production, robust outdoor material (artificial grass) and solar cell. A technoeconomic analysis of photoelectrochemical (PEC) and photovoltaic-electrolytic (PV-E) solar-hydrogen production of 10 000 kg H 2 day −1 (3.65 kilotons per year) was performed to assess the economics of each technology, and to provide a basis for comparison between these technologies as well as within the broader energy landscape. Two PEC systems, differentiated primarily by the extent of solar concentration (unconcentrated and 10× concentrated) and two PV-E systems, differentiated by the degree of grid connectivity (unconnected and grid supplemented), were analyzed. In each case, a base-case system that used established designs and materials was compared to prospective systems that might be envisioned and developed in the future with the goal of achieving substantially lower overall system costs. With identical overall plant efficiencies of 9.8%, the unconcentrated PEC and non-grid connected PV-E system base-case capital expenses for the rated capacity of 3.65 kilotons H 2 per year were \)205 MM ($293 per m 2 of solar collection area (m S −2 ), $14.7 W H2,P −1 ) and $260 MM ($371 m S −2 , $18.8 W H2,P −1 ), respectively. The untaxed, plant-gate levelized costs for the hydrogen product (LCH) were $11.4 kg −1 and $12.1 kg −1 for the base-case PEC and PV-E systems, respectively. The 10× concentrated PEC base-case system capital cost was $160 MM ($428 m S −2 , $11.5 W H2,P −1 ) and for an efficiency of 20% the LCH was $9.2 kg −1 . Likewise, the grid supplemented base-case PV-E system capital cost was $66 MM ($441 m S −2 , $11.5 W H2,P −1 ), and with solar-to-hydrogen and grid electrolysis system efficiencies of 9.8% and 61%, respectively, the LCH was $6.1 kg −1 . As a benchmark, a proton-exchange membrane (PEM) based grid-connected electrolysis system was analyzed. Assuming a system efficiency of 61% and a grid electricity cost of $0.07 kWh −1 , the LCH was $5.5 kg −1 . A sensitivity analysis indicated that, relative to the base-case, increases in the system efficiency could effect the greatest cost reductions for all systems, due to the areal dependencies of many of the components. The balance-of-systems (BoS) costs were the largest factor in differentiating the PEC and PV-E systems. No single or combination of technical advancements based on currently demonstrated technology can provide sufficient cost reductions to allow solar hydrogen to directly compete on a levelized cost basis with hydrogen produced from fossil energy. Specifically, a cost of CO 2 greater than ∼$800 (ton CO 2 ) −1 was estimated to be necessary for base-case PEC hydrogen to reach price parity with hydrogen derived from steam reforming of methane priced at $12 GJ −1 ($1.39 (kg H 2 ) −1 ). A comparison with low CO 2 and CO 2 -neutral energy sources indicated that base-case PEC hydrogen is not currently cost-competitive with electrolysis using electricity supplied by nuclear power or from fossil-fuels in conjunction with carbon capture and storage. Solar electricity production and storage using either batteries or PEC hydrogen technologies are currently an order of magnitude greater in cost than electricity prices with no clear advantage to either battery or hydrogen storage as of yet. Significant advances in PEC technology performance and system cost reductions are necessary to enable cost-effective PEC-derived solar hydrogen for use in scalable grid-storage applications as well as for use as a chemical feedstock precursor to CO 2 -neutral high energy-density transportation fuels. Hence such applications are an opportunity for foundational research to contribute to the development of disruptive approaches to solar fuels generation systems that can offer higher performance at much lower cost than is provided by current embodiments of solar fuels generators. Efforts to directly reduce CO 2 photoelectrochemically or electrochemically could potentially produce products with higher value than hydrogen, but many, as yet unmet, challenges include catalytic efficiency and selectivity, and CO 2 mass transport rates and feedstock cost. Major breakthroughs are required to obtain viable economic costs for solar hydrogen production, but the barriers to achieve cost-competitiveness with existing large-scale thermochemical processes for CO 2 reduction are even greater.
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                Author and article information

                Journal
                EESNBY
                Energy & Environmental Science
                Energy Environ. Sci.
                Royal Society of Chemistry (RSC)
                1754-5692
                1754-5706
                January 16 2019
                2019
                : 12
                : 1
                : 19-40
                Affiliations
                [1 ]Department of Chemical Engineering
                [2 ]Imperial College London
                [3 ]UK
                [4 ]Sustainable Gas Institute
                [5 ]Department of Earth Science and Engineering
                Article
                10.1039/C8EE02079E
                bcf5bc5a-aeb3-40f7-9149-586ffaddae34
                © 2019

                http://rsc.li/journals-terms-of-use

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