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      Recent progress on sonochemical production for the synthesis of efficient photocatalysts and the impact of reactor design

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          Highlights

          • Sonochemical synthesis of photocatalysts is a promising green field for the removal of toxic substances.

          • Sonochemistry affects the structure of the synthesized nanoparticles in favour of photocatalytic experiments.

          • Batch and continuous flow reactors are the most studied systems.

          • Continuous flow reactors are used both for the synthesis and the photocatalytic experiments.

          • Microflow reactors offer commercial-scale advantages.

          Abstract

          Sonochemical-assisted synthesis has flourished recently for the design of photocatalysts. The main power used is ultrasound that allows the nanomaterials shape and size modification and control. This review highlights the effect in formation mechanism by ultrasound application and the most common photocatalysts that were prepared via sonochemical techniques. Moreover, the challenge for the suitable reactor design for the synthesis of materials or for their photocatalytic evaluation is discussed since the most prominent reactor systems, batch, and continuous flow, has both advantages and drawbacks. This work summarises the significance of sonochemical synthesis for photocatalytic materials as a green technology that needs to be further investigated for the preparation of new materials and the scale up of developed reactor systems to meet industrial needs.

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          Most cited references117

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          Green process innovation, green product innovation, and corporate financial performance: A content analysis method

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            Sonochemical synthesis of nanomaterials.

            High intensity ultrasound can be used for the production of novel materials and provides an unusual route to known materials without bulk high temperatures, high pressures, or long reaction times. Several phenomena are responsible for sonochemistry and specifically the production or modification of nanomaterials during ultrasonic irradiation. The most notable effects are consequences of acoustic cavitation (the formation, growth, and implosive collapse of bubbles), and can be categorized as primary sonochemistry (gas-phase chemistry occurring inside collapsing bubbles), secondary sonochemistry (solution-phase chemistry occurring outside the bubbles), and physical modifications (caused by high-speed jets or shock waves derived from bubble collapse). This tutorial review provides examples of how the chemical and physical effects of high intensity ultrasound can be exploited for the preparation or modification of a wide range of nanostructured materials.
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              Power ultrasound in organic synthesis: moving cavitational chemistry from academia to innovative and large-scale applications.

              Ultrasound, an efficient and virtually innocuous means of activation in synthetic chemistry, has been employed for decades with varied success. Not only can this high-energy input enhance mechanical effects in heterogeneous processes, but it is also known to induce new reactivities leading to the formation of unexpected chemical species. What makes sonochemistry unique is the remarkable phenomenon of cavitation, currently the subject of intense research which has already yielded thought-provoking results. This critical review is aimed at discussing the present status of cavitational chemistry and some of the underlying phenomena, and to highlight some recent applications and trends in organic sonochemistry, especially in combination with other sustainable technologies. (151 references.).
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                Author and article information

                Contributors
                Journal
                Ultrason Sonochem
                Ultrason Sonochem
                Ultrasonics Sonochemistry
                Elsevier
                1350-4177
                1873-2828
                28 September 2023
                November 2023
                28 September 2023
                : 100
                : 106610
                Affiliations
                [a ]Department of Chemical Engineering Cyprus University of Technology, 57 Corner of Athinon and Anexartisias, 3036 Limassol, Cyprus
                [b ]School of Engineering and Materials Science, Queen Mary University of London, London E1 4NS, the United Kingdom of Great Britain and Northern Ireland
                [c ]Department of Chemical Engineering, University College London, London WCIE 7JE, the United Kingdom of Great Britain and Northern Ireland
                [d ]Dipartimento di Chimica, Universitá degli Studi di Milano, via Golgi, 20133 Milan, Italy
                [e ]Environment & Life Sciences Research Centre, Kuwait Institute for Scientific Research, P.O. Box: 24885, Safat 13109, Kuwait
                [f ]Department of Industrial Chemistry “Toso Montanari”, University of Bologna, viale Risorgimento 4 40136 Bologna, Italy
                [g ]Center for Chemical Catalysis – C3, University of Bologna, viale Risorgimento 4 40136 Bologna, Italy
                Author notes
                [1]

                These authors share first authorship.

                Article
                S1350-4177(23)00322-X 106610
                10.1016/j.ultsonch.2023.106610
                10568290
                37806038
                bcafaafa-2017-45a6-b7a4-efaacf5fdd48
                © 2023 The Author(s)

                This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 25 July 2023
                : 18 September 2023
                : 19 September 2023
                Categories
                Original Research Article

                sonochemical synthesis,photocatalysts,nanoparticles,flow reactors,microflow reactors

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