Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles <i>via</i> Transition Metal-Catalyzed Cascade C-H Activation/Carbene Insertion/Annulation Reactions

Xiang, Yunyu; Wang, Cong; Ding, Qiuping; Peng, Yiyuan

doi:10.1002/adsc.201800960

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Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal-Catalyzed Cascade C-H Activation/Carbene Insertion/Annulation Reactions

Author(s): Yunyu Xiang ¹ , Cong Wang ¹ , Qiuping Ding ¹ , Yiyuan Peng ¹

Publication date (Electronic): November 27 2018

Journal: Advanced Synthesis & Catalysis

Publisher: Wiley

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Most cited references 141

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Occurrence, biogenesis, and synthesis of biologically active carbazole alkaloids.

Arndt W Schmidt, Kethiri R Reddy, Hans-Joachim Knölker (2012)

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Isolation and synthesis of biologically active carbazole alkaloids.

Hans-Joachim Knölker, Kethiri R Reddy (2002)

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Isoquinoline synthesis via rhodium-catalyzed oxidative cross-coupling/cyclization of aryl aldimines and alkynes.

Nicolas Guimond, Keith Fagnou (2009)

A general rhodium-catalyzed oxidative coupling reaction between internal alkynes and aryl aldimines is described. This process affords 3,4-disubstituted isoquinolines in good yield and high regioselectivity. Preliminary mechanistic studies suggest that the C-N bond formation arises from the reductive elimination of a rhodium(III) species.

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Author and article information

Journal

Title: Advanced Synthesis & Catalysis

Abbreviated Title: Adv. Synth. Catal.

Publisher: Wiley

ISSN: 16154150

Publication date Created: March 05 2019

Publication date (Print): March 05 2019

Publication date (Electronic): November 27 2018

Volume: 361

Issue: 5

Pages: 919-944

Affiliations

[1 ]Key Laboratory of Small Functional Organic Molecule, Ministry of Education and Jiangxi's Key Laboratory of Green Chemistry; Jiangxi Normal University; Nanchang, Jiangxi 330022 People's Republic of China