Chromatographic techniques for the analysis of organophosphate pesticides with their extraction approach: a review (2015–2020)

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Abstract

In agriculture, a wide range of OPPs has been employed to boost crop yield, quality, and storage life.

Abstract

In agriculture, a wide range of OPPs has been employed to boost crop yield, quality, and storage life. However, due to the ever-increasing population and rapid urbanization, pesticide use has surged in recent years. These compounds are exceedingly poisonous to humans, and despite the fact that specific legislation prohibits their use, the frequency of toxic and/or fatal incidents, as well as current statistics, suggest that they are currently accessible. As a result, determining the exposure to these substances as well as their detection (and that of their metabolites) in different types of exposed samples has become a hot issue in terms of quality and safety concerns. However, developing tools for the evaluation of these substances is a critical challenge for laboratories. Various chromatographic-based methods reported in the period of 2015–2020 have been developed, which are summarized and critically reviewed in this article, including the extraction of the target OPPs from different kinds of matrices. A comparison among the extraction and analysis techniques has been made in the current review article.

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Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles

Aldenor Santos, Gisele O. da Rocha, Jailson de Andrade (2019)

Polycyclic aromatic compounds (PACs) are known due to their mutagenic activity. Among them, 2-nitrobenzanthrone (2-NBA) and 3-nitrobenzanthrone (3-NBA) are considered as two of the most potent mutagens found in atmospheric particles. In the present study 2-NBA, 3-NBA and selected PAHs and Nitro-PAHs were determined in fine particle samples (PM 2.5) collected in a bus station and an outdoor site. The fuel used by buses was a diesel-biodiesel (96:4) blend and light-duty vehicles run with any ethanol-to-gasoline proportion. The concentrations of 2-NBA and 3-NBA were, on average, under 14.8 µg g−1 and 4.39 µg g−1, respectively. In order to access the main sources and formation routes of these compounds, we performed ternary correlations and multivariate statistical analyses. The main sources for the studied compounds in the bus station were diesel/biodiesel exhaust followed by floor resuspension. In the coastal site, vehicular emission, photochemical formation and wood combustion were the main sources for 2-NBA and 3-NBA as well as the other PACs. Incremental lifetime cancer risk (ILCR) were calculated for both places, which presented low values, showing low cancer risk incidence although the ILCR values for the bus station were around 2.5 times higher than the ILCR from the coastal site.

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Determination of organic compounds in water using dispersive liquid-liquid microextraction.

Mohammad Rezaee, Yaghoub Assadi, Mohammad-Reza Milani Hosseini … (2006)

A new microextraction technique termed dispersive liquid-liquid microextraction (DLLME) was developed. DLLME is a very simple and rapid method for extraction and preconcentration of organic compounds from water samples. In this method, the appropriate mixture of extraction solvent (8.0 microL C2Cl4) and disperser solvent (1.00 mL acetone) are injected into the aqueous sample (5.00 mL) by syringe, rapidly. Therefore, cloudy solution is formed. In fact, it is consisted of fine particles of extraction solvent which is dispersed entirely into aqueous phase. After centrifuging, the fine particles of extraction solvent are sedimented in the bottom of the conical test tube (5.0 +/- 0.2 microL). The performance of DLLME is illustrated with the determination of polycyclic aromatic hydrocarbons (PAHs) in water samples by using gas chromatography-flame ionization detection (GC-FID). Some important parameters, such as kind of extraction and disperser solvent and volume of them, and extraction time were investigated. Under the optimum conditions the enrichment factor ranged from 603 to 1113 and the recovery ranged from 60.3 to 111.3%. The linear range was 0.02-200 microg/L (four orders of magnitude) and limit of detection was 0.007-0.030 microg/L for most of analytes. The relative standard deviations (RSDs) for 2 microg/L of PAHs in water by using internal standard were in the range 1.4-10.2% (n = 5). The recoveries of PAHs from surface water at spiking level of 5.0 microg/L were 82.0-111.0%. The ability of DLLME technique in the extraction of other organic compounds such as organochlorine pesticides, organophosphorus pesticides and substituted benzene compounds (benzene, toluene, ethyl benzene, and xylenes) from water samples were studied. The advantages of DLLME method are simplicity of operation, rapidity, low cost, high recovery, and enrichment factor.

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Fast and Easy Multiresidue Method Employing Acetonitrile Extraction/Partitioning and “Dispersive Solid-Phase Extraction” for the Determination of Pesticide Residues in Produce

Michelangelo Anastassiades, Steven J Lehotay, Darinka Stajnbaher … (2003)

A simple, fast, and inexpensive method for the determination of pesticide residues in fruits and vegetables is introduced. The procedure involves initial single-phase extraction of 10 g sample with 10 mL acetonitrile, followed by liquid–liquid partitioning formed by addition of 4 g anhydrous MgSO4 plus 1 g NaCl. Removal of residual water and cleanup are performed simultaneously by using a rapid procedure called dispersive solid-phase extraction (dispersive-SPE), in which 150 mg anhydrous MgSO4 and 25 mg primary secondary amine (PSA) sorbent are simply mixed with 1 mL acetonitrile extract. The dispersive-SPE with PSA effectively removes many polar matrix components, such as organic acids, certain polar pigments, and sugars, to some extent from the food extracts. Gas chromatography/mass spectrometry (GC/MS) is then used for quantitative and confirmatory analysis of GC-amenable pesticides. Recoveries between 85 and 101% (mostly >95%) and repeatabilities typically <5% have been achieved for a wide range of fortified pesticides, including very polar and basic compounds such as methamidophos, acephate, omethoate, imazalil, and thiabendazole. Using this method, a single chemist can prepare a batch of 6 previously chopped samples in <30 min with approximately $1 (U.S.) of materials per sample.

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Author and article information

Contributors

Deepika Kathuria: (View ORCID Profile)

Beant Kaur Billing: (View ORCID Profile)

Journal

Journal ID (publisher-id): AMNECT

Title: Analytical Methods

Abbreviated Title: Anal. Methods

Publisher: Royal Society of Chemistry (RSC)

ISSN (Print): 1759-9660

ISSN (Electronic): 1759-9679

Publication date Created: January 27 2022

Publication date (Electronic): 2022

Volume: 14

Issue: 4

Pages: 322-358

Affiliations

[1 ]University Centre for Research and Development, Chandigarh University, Gharuan, Punjab 140413, India

Article

DOI: 10.1039/D1AY01404H

PubMed ID: 34994766

SO-VID: 949917d6-dbb3-43c3-a305-ed2d2378c05e

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http://rsc.li/journals-terms-of-use

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