Simultaneous removal of cadmium ions and phenol with MEUF using SDS and mixed surfactants

The removal characteristics of arsenate using micellar-enhanced ultrafiltration (MEUF) were investigated. Among four different cationic surfactants used, hexadecylpyridinium chloride (CPC) showed the highest removal efficiency of arsenic (96%), and the removal efficiency with hexadecyltrimethylammonium bromide (CTAB) was 94%. But the removal efficiency with benzalkonium chloride (BC) was the lowest (57%) due to higher critical micelle concentration (CMC) of BC than those of other surfactants. Over 80% of arsenic was removed with octadecylamine acetate (ODA). On the effect of solution pH on the arsenic removal, since the valance of arsenate decreases from trivalent to monovalent as pH decreases, the removal was reduced at lower pH. The presence of 0.45mM of nitrate and 0.01mM of phosphate reduced the removal efficiency by 5-8%. This decrease was because of the competition between the arsenate, nitrate and phosphate for the binding sites of the surfactant micelle. Similar decrease in the removal of arsenate was observed with CPC, CTAB and ODA in the presence of these anions. In cross-flow filtration, the removal efficiency of arsenic was similar to that in the dead-end system. However, the decline in flux was less than that in dead-end filtration. In order to lower the concentration of the surfactant in the effluent, the effluent was treated with powdered activated carbon (PAC) before discharging to the environment. Over 98% surfactant was removed with 1gl(-1) of PAC. In conclusions, the MEUF is considered as a feasible process using CPC or CTAB to remove the arsenate from groundwater compared with the other solid based adsorbent processes.

Single and simultaneous removal of Cd(2+) and methylene blue (MB) with sodium dodecyl sulfate (SDS) by micellar-enhanced ultrafiltration under different experimental conditions was investigated. In single removal process, with initial SDS concentration increasing, the removal efficiency of Cd(2+) and MB kept increasing and then decreased. When the initial concentrations of SDS and Cd(2+) were 1.0 cmc and 50 mg L(-1), respectively, the maximum removal efficiency of Cd(2+) was obtained as 99.2%. Removal efficiency of MB could achieve more than 99.9% with initial SDS concentration below 2.0 cmc. As compared with single Cd(2+) removal, the removal efficiency of Cd(2+) in the presence of MB was slightly higher with initial SDS concentration below 1.0 cmc, while decreased with the SDS concentration above 1.0 cmc. The maximum removal efficiency of Cd(2+) was 98.8% when initial concentrations of SDS and MB were 1.0 cmc and 4 mg L(-1), respectively. The removal efficiency of MB in the presence of Cd(2+) could achieve higher than 96.5%, which was only 3.4% less than the optimum result of the single removal. Meanwhile, effect of pH on removal efficiency of Cd(2+) was more significant than that of MB.