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      Octahedral Pd2+ Coordination and Ferromagnetic Ordering in Pd(S2O7)

      , , ,
      Angewandte Chemie International Edition
      Wiley

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          Heteropoly-13-palladates(II) [Pd(II)(13)(As(V)Ph)(8)O(32)](6-) and [Pd(II)(13)Se(IV)(8)O(32)](6-).

          Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.
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            The Cluster Ion[Pt12O8(SO4)12]4−

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              Das Clusteranion[Pt12O8(SO4)12]4−

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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley
                14337851
                February 27 2012
                February 27 2012
                November 30 2011
                : 51
                : 9
                : 2204-2207
                Article
                10.1002/anie.201107197
                7942cae1-0eac-4842-bb49-45e54f1e90b0
                © 2011

                http://doi.wiley.com/10.1002/tdm_license_1.1

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