Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(ii) Schiff base complex via spontaneous symmetry breaking

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Abstract

A homochiral helical coordination polymer of copper( ii) has been synthesized using achiral precursors. End-to-end cyanate bridges mediate ferromagnetic exchange interactions among copper( ii) centres.

Abstract

A homochiral helical coordination polymer of copper( ii) has been synthesized using achiral precursors via spontaneous symmetry breaking and has been confirmed by single crystal X-ray diffraction and solid-state CD spectroscopy. The variable temperature magnetic measurements indicate the presence of weak ferromagnetic exchange interactions mediated by end-to-end cyanate bridges ( J = +0.12 cm ⁻¹).

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Author and article information

Journal

Journal ID (publisher-id): ICHBD9

Title: Dalton Transactions

Abbreviated Title: Dalton Trans.

Publisher: Royal Society of Chemistry (RSC)

ISSN (Print): 1477-9226

ISSN (Electronic): 1477-9234

Publication date Created: 2015

Publication date (Print): 2015

Volume: 44

Issue: 2

Pages: 493-497

Article

DOI: 10.1039/C4DT03166K

SO-VID: 531d5ea9-a9b2-45ed-a1ef-4a3aeed3bcfd

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