A computational model using Large Eddy Simulation (LES) for turbulence modelling was implemented, by means of the Eddy Dissipation Concept (EDC) combustion model using the fireFoam solver. A small methanol pool fire experiment was simulated in order to validate and compare the numerical results, hence trying to validate the effectiveness of the solver. A detailed convergence analysis is performed showing that a mesh of approximately two million elements is sufficient to achieve satisfactory numerical results (including chemical kinetics). A good agreement was achieved with some of the experimental and previous computational results, especially in the prediction of the flame height and the average temperature contours.