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      A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes†

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          Abstract

          A series of complexes of the type [Cu(X)(NHC)] (X = I, Br, Cl, NHC = N-heterocyclic carbene) was synthesised using a one-pot, mild and user-friendly (aerobic, tech. grade solvents) procedure.

          Abstract

          A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

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          Metal N-heterocyclic carbene complexes as potential antitumor metallodrugs.

          Wukun Liu, Ronald Gust (2013)
          The discovery of cisplatin's antitumor activity in 1969 prompted the search for novel metal-containing complexes as potential anticancer drugs. Among these novel complexes, metal N-heterocyclic carbene (NHC) complexes have recently gained considerable attention because they perfectly fit prerequisites for efficient drug design and fast optimization. Moreover, most of them have shown higher cytotoxicity than cisplatin. This review describes the advances that have been achieved in using transition metal (Ag, Au, Pt, Pd, Cu, Ni, and Ru) complexes containing NHC ligands as antitumor agents. Their modes of action at the cellular lever are further discussed. All these initial achievements clearly demonstrate the great potential of metal-NHC complexes as antitumor agents.
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            Design and properties of functional nanotubes from the self-assembly of cyclic peptide templates.

            Robert B. Chapman, Maarten Danial, Ming Liang Koh … (2012)
            β-Sheet forming self assembling cyclic peptides offer a versatile scaffold for the construction and control of hydrogen-bonded nanotube assemblies. These structures have major advantages over other nanoscale tubular structures, including sub-nanometer control over the internal diameter, and the ability to control internal and external chemical functionality. This Tutorial Review presents an overview of nanotubes derived from this class of cyclic peptides. The design rationale for functional nanotubes based on cyclic peptide ring size and chemical functionality is discussed. Additionally, we highlight the recent expansion of the nanotube toolbox through conjugation of (macro)molecules to the cyclic peptides. These provide additional functionality and control nanotube dimensions that could potentially prove beneficial in future applications.
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              Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

              Xile Hu, Brandi M. Cossairt, Bruce Brunschwig … (2005)
              Article 0 comments Cited 67 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (nlm-ta): Chem Commun (Camb)
                Journal ID (iso-abbrev): Chem. Commun. (Camb.)
                Title: Chemical Communications (Cambridge, England)
                Publisher: Royal Society of Chemistry
                ISSN (Print): 1359-7345
                ISSN (Electronic): 1364-548X
                Publication date (Print): 18 November 2013
                Publication date (Electronic): 1 October 2013
                Volume: 49
                Issue: 89
                Page: 10435
                Affiliations
                [a ] EaStCHEM School of Chemistry , University of St Andrews , St Andrews , KY16 9ST , UK . Email: cc111@ 123456st-andrews.ac.uk ; Fax: +44 (0)1334463808
                Article
                Publisher ID: c3cc45488f
                DOI: 10.1039/c3cc45488f
                PMC ID: 4155829
                PubMed ID: 24087835
                SO-VID: 6a149227-5c4a-44fc-8ebb-f6f3d28e32cd
                Copyright © This journal is © The Royal Society of Chemistry 2013
                License:

                This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License ( http://creativecommons.org/licenses/by-nc/2.0/uk/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                Date received : 19 July 2013
                Date accepted : 12 August 2013
                Categories
                Subject: Chemistry

                Notes

                †Electronic supplementary information (ESI) available: Optimisation details and full characterisation data. CCDC 940850–940853. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45488f


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