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      p-wave triggered superconductivity in single-layer graphene on an electron-doped oxide superconductor

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          Abstract

          Electron pairing in the vast majority of superconductors follows the Bardeen–Cooper–Schrieffer theory of superconductivity, which describes the condensation of electrons into pairs with antiparallel spins in a singlet state with an s-wave symmetry. Unconventional superconductivity was predicted in single-layer graphene (SLG), with the electrons pairing with a p-wave or chiral d-wave symmetry, depending on the position of the Fermi energy with respect to the Dirac point. By placing SLG on an electron-doped (non-chiral) d-wave superconductor and performing local scanning tunnelling microscopy and spectroscopy, here we show evidence for a p-wave triggered superconducting density of states in SLG. The realization of unconventional superconductivity in SLG offers an exciting new route for the development of p-wave superconductivity using two-dimensional materials with transition temperatures above 4.2 K.

          Abstract

          Unconventional superconductivity may be triggered when graphene is deposited on a high temperature superconductor. Here, Di Bernardo et al. observe spectroscopic evidence for p-wave superconductivity in single layer graphene on an electron-doped cuprate superconductor.

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          Most cited references64

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          Two Dimensional Atomic Crystals

          We report free-standing atomic crystals that are strictly 2D and can be viewed as individual atomic planes pulled out of bulk crystals or as unrolled single-wall nanotubes. By using micromechanical cleavage, we have prepared and studied a variety of 2D crystals, including single layers of boron nitride, graphite, several dichalcogenides and complex oxides. These atomically-thin sheets (essentially gigantic 2D molecules unprotected from the immediate environment) are stable under ambient conditions, exhibit high crystal quality and are continuous on a macroscopic scale.
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            Transition from metallic to tunneling regimes in superconducting microconstrictions: Excess current, charge imbalance, and supercurrent conversion

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              Roll-to-roll production of 30-inch graphene films for transparent electrodes.

              The outstanding electrical, mechanical and chemical properties of graphene make it attractive for applications in flexible electronics. However, efforts to make transparent conducting films from graphene have been hampered by the lack of efficient methods for the synthesis, transfer and doping of graphene at the scale and quality required for applications. Here, we report the roll-to-roll production and wet-chemical doping of predominantly monolayer 30-inch graphene films grown by chemical vapour deposition onto flexible copper substrates. The films have sheet resistances as low as approximately 125 ohms square(-1) with 97.4% optical transmittance, and exhibit the half-integer quantum Hall effect, indicating their high quality. We further use layer-by-layer stacking to fabricate a doped four-layer film and measure its sheet resistance at values as low as approximately 30 ohms square(-1) at approximately 90% transparency, which is superior to commercial transparent electrodes such as indium tin oxides. Graphene electrodes were incorporated into a fully functional touch-screen panel device capable of withstanding high strain.
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                Author and article information

                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group
                2041-1723
                19 January 2017
                2017
                : 8
                : 14024
                Affiliations
                [1 ]Department of Materials Science and Metallurgy, University of Cambridge , 27 Charles Babbage Road, Cambridge CB3 0FS, UK
                [2 ]Racah Institute of Physics and the Hebrew University Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem , Jerusalem 91904, Israel
                [3 ]Cambridge Graphene Centre, University of Cambridge , Cambridge CB3 0FA, UK
                [4 ]Department of Physics, Norwegian University of Science and Technology , N-7491 Trondheim, Norway
                Author notes
                [*]

                Present address: Nokia Bell Labs, Broers Building, Cambridge CB3 0FA, UK

                Author information
                http://orcid.org/0000-0002-2912-2023
                Article
                ncomms14024
                10.1038/ncomms14024
                5253682
                28102222
                6713aed4-9c92-4eda-8676-64944b5c54a0
                Copyright © 2017, The Author(s)

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 09 June 2016
                : 21 November 2016
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