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      Review of photocatalytic water-splitting methods for sustainable hydrogen production : Review: photocatalysis for sustainable hydrogen

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      International Journal of Energy Research
      Wiley-Blackwell

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          Review and evaluation of hydrogen production methods for better sustainability

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            Facet effect of single-crystalline Ag3PO4 sub-microcrystals on photocatalytic properties.

            We recently reported that Ag(3)PO(4) exhibits excellent photooxidative capabilities for O(2) evolution from water and organic dye decomposition under visible-light irradiation. However, very little is known about the shape and facet effects of Ag(3)PO(4) crystals on their photocatalytic properties. Herein we have developed a facile and general route for high-yield fabrication of single-crystalline Ag(3)PO(4) rhombic dodecahedrons with only {110} facets exposed and cubes bounded entirely by {100} facets. Moreover, studies of their photocatalytic performance have indicated that rhombic dodecahedrons exhibit much higher activities than cubes for the degradation of organic contaminants, which may be primarily ascribed to the higher surface energy of {110} facets (1.31 J/m(2)) than of {100} facets (1.12 J/m(2)). © 2011 American Chemical Society
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              Photochemical splitting of water for hydrogen production by photocatalysis: A review

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                Author and article information

                Journal
                International Journal of Energy Research
                Int. J. Energy Res.
                Wiley-Blackwell
                0363907X
                September 2016
                September 2016
                : 40
                : 11
                : 1449-1473
                Article
                10.1002/er.3549
                516b9095-cb84-4fa4-a88e-e1dac171f269
                © 2016

                http://doi.wiley.com/10.1002/tdm_license_1.1

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