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      Localization and Directionality of Surface Transport in Bi 2Te 3 Ordered 3D Nanonetworks

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          Abstract

          The resistance of an ordered 3D-Bi 2Te 3 nanowire nanonetwork was studied at low temperatures. Below 50 K the increase in resistance was found to be compatible with the Anderson model for localization, considering that conduction takes place in individual parallel channels across the whole sample. Angle-dependent magnetoresistance measurements showed a distinctive weak antilocalization characteristic with a double feature that we could associate with transport along two perpendicular directions, dictated by the spatial arrangement of the nanowires. The coherence length obtained from the Hikami–Larkin–Nagaoka model was about 700 nm across transversal nanowires, which corresponded to approximately 10 nanowire junctions. Along the individual nanowires, the coherence length was greatly reduced to about 100 nm. The observed localization effects could be the reason for the enhancement of the Seebeck coefficient observed in the 3D-Bi 2Te 3 nanowire nanonetwork compared to individual nanowires.

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          Topological insulators in Bi2Se3, Bi2Te3 and Sb2Te3 with a single Dirac cone on the surface

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            Experimental realization of a three-dimensional topological insulator, Bi2Te3.

            Three-dimensional topological insulators are a new state of quantum matter with a bulk gap and odd number of relativistic Dirac fermions on the surface. By investigating the surface state of Bi2Te3 with angle-resolved photoemission spectroscopy, we demonstrate that the surface state consists of a single nondegenerate Dirac cone. Furthermore, with appropriate hole doping, the Fermi level can be tuned to intersect only the surface states, indicating a full energy gap for the bulk states. Our results establish that Bi2Te3 is a simple model system for the three-dimensional topological insulator with a single Dirac cone on the surface. The large bulk gap of Bi2Te3 also points to promising potential for high-temperature spintronics applications.
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              Spin-Orbit Interaction and Magnetoresistance in the Two Dimensional Random System

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                Author and article information

                Journal
                ACS Nano
                ACS Nano
                nn
                ancac3
                ACS Nano
                American Chemical Society
                1936-0851
                1936-086X
                06 July 2023
                12 September 2023
                : 17
                : 17
                : 16960-16967
                Affiliations
                [§ ]Instituto de Micro y Nanotecnología, IMN-CNM, CSIC (CEI UAM+CSIC) Isaac Newton 8 , E-28760, Tres Cantos, Madrid, Spain
                []Institute for Metallic Materials, IFW-Dresden , Helmholtzstrasse 20, 01069 Dresden, Germany
                [|| ]LENS-MIND, Department of Electronics and Biomedical Engineering, Universitat de Barcelona , 08028 Barcelona, Spain
                [¥ ]Institute of Nanoscience and Nanotechnology (IN2UB), Universitat de Barcelona , 08028 Barcelona, Spain
                [¢ ]Scientific & Technical Resources, Universitat Rovira i Virgili , 43007 Tarragona, Spain
                []Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz , Cádiz 11510, Spain
                Author notes
                Author information
                https://orcid.org/0000-0003-1777-7126
                https://orcid.org/0000-0002-5697-0554
                https://orcid.org/0000-0002-4047-8362
                https://orcid.org/0000-0003-2560-8015
                https://orcid.org/0000-0002-5687-3674
                Article
                10.1021/acsnano.3c04160
                10510701
                37410703
                4bf0e766-6082-4dc5-abfa-52f1470d55a4
                © 2023 The Authors. Published by American Chemical Society

                Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained ( https://creativecommons.org/licenses/by/4.0/).

                History
                : 09 May 2023
                : 30 June 2023
                Funding
                Funded by: H2020 European Research Council, doi 10.13039/100010663;
                Award ID: 101052603
                Funded by: European Regional Development Fund, doi 10.13039/501100008530;
                Award ID: FEDER-UCA18-107139
                Funded by: Ministerio de Ciencia e Innovación, doi 10.13039/501100004837;
                Award ID: PID2020-118430GB-100
                Funded by: Ministerio de Ciencia e Innovación, doi 10.13039/501100004837;
                Award ID: PID2019-106165GB-C21
                Funded by: Consejo Superior de Investigaciones Científicas, doi 10.13039/501100003339;
                Award ID: NA
                Funded by: Consejería de Economía, Conocimiento, Empresas y Universidad, Junta de Andalucía, doi 10.13039/100016970;
                Award ID: FEDER-UCA18-107139
                Categories
                Article
                Custom metadata
                nn3c04160
                nn3c04160

                Nanotechnology
                metamaterials,bismuth telluride,3d-aao,nanonetwork,surface transport,localization effects

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