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      Biopolymer-based electrospun fibers in electrochemical devices: versatile platform for energy, environment, and health monitoring

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          Abstract

          Electrochemical power tools, fabricated using the natural-based electrospun fibers, are regarded as essential keys in a world that is becoming increasingly reliant on fossil fuels in order to meet the challenges of rapidly depleting fossil fuel supplies.

          Abstract

          Electrochemical power tools are regarded as essential keys in a world that is becoming increasingly reliant on fossil fuels in order to meet the challenges of rapidly depleting fossil fuel supplies. Additionally, due to the industrialization of societies and the growth of diseases, the need for sensitive, reliable, inexpensive, and portable sensors and biosensors for noninvasive monitoring of human health and environmental pollution is felt more than ever before. In recent decades, electrospun fibers have emerged as promising candidates for the fabrication of highly efficient electrochemical devices, such as actuators, batteries, fuel cells, supercapacitors, and biosensors. Meanwhile, the use of synthetic polymers in the fabrication of versatile electrochemical devices has raised environmental concerns, leading to an increase in the quest for natural polymers. Natural polymers are primarily derived from microorganisms and plants. Despite the challenges of processing bio-based electrospun fibers, employing natural nanofibers in the fabrication of electrochemical devices has garnered tremendous attention in recent years. Here, various natural polymers and the strategies employed to fabricate various electrospun biopolymers are briefly covered. The recent advances and research strategies used to apply the bio-based electrospun membranes in different electrochemical devices are carefully summarized, along with the scopes in various advanced technologies. A comprehensive and critical discussion about the use of biopolymer-based electrospun fibers as the potential alternative to non-renewable ones in future technologies is briefly highlighted. This review will serve as a field opening platform for using different biopolymer-based electrospun fibers to advance the electrochemical device-based renewable and sustainable technologies, which will be of high interest to a large community. Accordingly, future studies should focus on feasible and cost-effective extraction of biopolymers from natural resources as well as fabrication of high-performance nanofibrous biopolymer-based components applicable in various electrochemical devices.

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          Most cited references272

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          Batteries and fuel cells for emerging electric vehicle markets

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            Carbons and electrolytes for advanced supercapacitors.

            Electrical energy storage (EES) is one of the most critical areas of technological research around the world. Storing and efficiently using electricity generated by intermittent sources and the transition of our transportation fleet to electric drive depend fundamentally on the development of EES systems with high energy and power densities. Supercapacitors are promising devices for highly efficient energy storage and power management, yet they still suffer from moderate energy densities compared to batteries. To establish a detailed understanding of the science and technology of carbon/carbon supercapacitors, this review discusses the basic principles of the electrical double-layer (EDL), especially regarding the correlation between ion size/ion solvation and the pore size of porous carbon electrodes. We summarize the key aspects of various carbon materials synthesized for use in supercapacitors. With the objective of improving the energy density, the last two sections are dedicated to strategies to increase the capacitance by either introducing pseudocapacitive materials or by using novel electrolytes that allow to increasing the cell voltage. In particular, advances in ionic liquids, but also in the field of organic electrolytes, are discussed and electrode mass balancing is expanded because of its importance to create higher performance asymmetric electrochemical capacitors. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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              Nitrogen-doped porous carbon nanofiber webs as anodes for lithium ion batteries with a superhigh capacity and rate capability.

              Nitrogen-doped carbon nanofiber webs (CNFWs) with high surface areas are successfully prepared by carbonization-activation of polypyrrole nanofiber webs with KOH. The as-obtained CNFWs exhibit a superhigh reversible capacity of 943 mAh g(-1) at a current density of 2 A g(-1) even after 600 cycles, which is ascribed to the novel porous nanostructure and high-level nitrogen doping. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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                Author and article information

                Contributors
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                Journal
                MHAOAL
                Materials Horizons
                Mater. Horiz.
                Royal Society of Chemistry (RSC)
                2051-6347
                2051-6355
                November 28 2022
                2022
                : 9
                : 12
                : 2914-2948
                Affiliations
                [1 ]Department of Textile Engineering, Amirkabir University of Technology, Tehran 159163-4311, Iran
                [2 ]Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
                [3 ]Istituto Italiano di Tecnologia, via Morego 30, Genova 16163, Italy
                [4 ]Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, I-16146 Genova, Italy
                [5 ]Faculty of Chemistry and Food Chemistry and Center for Advancing Electronics Dresden (cfaed), Technische Universitate Dresden, Dresden 01062, Germany
                [6 ]Department of Physics, National Institute of Technology, Kurukshetra, Haryana, India
                [7 ]School of Mechanical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan-si, Gyeongsangbuk-do, 38541, South Korea
                [8 ]Research Cell & Department of Physics, Bhagini Nivedita College, University of Delhi, Delhi 110043, India
                [9 ]Mads Clausen Institute, NanoSYD, Smart Materials, University of Southern Denmark, Alsion 2, 6400, Sønderborg, Denmark
                [10 ]NanoBioTech Laboratory, Health Systems Engineering, Department of Natural Sciences, Florida Polytechnic University, Lakeland, Florida, USA
                [11 ]School of Engineering, University of Petroleum and Energy Studies (UPES), Dehradun, Uttarakhand, India
                [12 ]Stanford Cardiovascular Institute, Stanford University School of Medicine, Stanford, CA 94305, USA
                [13 ]Department of Medicine, Stanford University School of Medicine, Stanford, CA 94305, USA
                Article
                10.1039/D2MH00879C
                36226580
                34f91876-2a8f-4603-9eeb-440ac09f7d27
                © 2022

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