Polymer ultrapermeability from the inefficient packing of 2D chains

McKeown, Neil B; Rose, Ian T.; Bezzu, C. Grazia; Carta, Mariolino; Comesaña-Gándara, Bibiana; Lasseuguette, Elsa; Ferrari, M. Chiara; Bernardo, Paola; Clarizia, Gabriele; Fuoco, Alessio; Jansen, Johannes C.; Hart, Kyle E.; Liyana-Arachchi, Thilanga P.; Colina, Coray M.

doi:10.1038/nmat4939

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Polymer ultrapermeability from the inefficient packing of 2D chains

Author(s): Ian Rose , C. Grazia Bezzu , Mariolino Carta , Bibiana Comesaña-Gándara , Elsa Lasseuguette , M. Chiara Ferrari , Paola Bernardo , Gabriele Clarizia , Alessio Fuoco , Johannes C. Jansen , Kyle E. Hart , Thilanga P. Liyana-Arachchi , Coray M. Colina , Neil B. McKeown

Publication date Created: July 31 2017

Publication date (Print): July 31 2017

Journal: Nature Materials

Publisher: Springer Nature

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Abstract

Polymer membranes were formed from the inefficient packing of 2D polymer chains in a 3D amorphous solid, forming small and large micropores that enable high gas selectivity and permeability. This strategy may be applied to other polymers.