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      Constructing Mechanochemical Durable and Self-Healing Superhydrophobic Surfaces

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          Abstract

          Bioinspired superhydrophobic surfaces have attracted great interest due to their special functions and wide applications. However, it is still a big challenge to construct a durable superhydrophobic coating for large-scale applications due to its easy destruction by the mechanochemical attack. In this mini-review, we present the state-of-the-art developments in the rational design of mechanochemical durable and self-healing superhydrophobic surfaces. First, the mechanically durable superhydrophobic surfaces are constructed to endure mechanical damage by adjusting the surface morphology and increasing the binding force between the substrates and the modified materials. Second, chemical damages also have been taken into consideration to develop chemically robust superhydrophobic surfaces, such as chemical etching, ultraviolet (UV)-light irradiation, and bioerosion, etc. Third, endowing superhydrophobic coatings with self-healing function can effectively improve the durability and prolong the lifespan of the coatings by releasing low-surface-energy agents or regenerating topographic structures. Finally, the challenges and future perspectives in developing super durable bioinspired superhydrophobic surfaces by structure design and chemistry control are discussed. The innovative points provided in this mini-review will provide deep fundamental insight for prolonging the lifetime of the superhydrophobic surfaces and enable their practical applications in the near future.

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          Most cited references29

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          All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance

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            Robust superhydrophobic TiO2@fabrics for UV shielding, self-cleaning and oil–water separation

            Multifunctional robust TiO 2 @fabrics with special wettability demonstrated potential applications for excellent UV shielding, effective self-cleaning, efficient oil–water separation and microfluidic management. Inspired by the surface geometry and composition of the lotus leaf with its self-cleaning behavior, in this work, a TiO 2 @fabric composite was prepared via a facile strategy for preparing marigold flower-like hierarchical TiO 2 particles through a one-pot hydrothermal reaction on a cotton fabric surface. In addition, a robust superhydrophobic TiO 2 @fabric was further constructed by fluoroalkylsilane modification as a versatile platform for UV shielding, self-cleaning and oil–water separation. The results showed TiO 2 particles were uniformly distributed on the fibre surface with a high coating density. In comparison with hydrophobic cotton fabric, the TiO 2 @fabric exhibited a high superhydrophobic activity with a contact angle of ∼160° and a sliding angle lower than 10°. The robust superhydrophobic fabric had high stability against repeated abrasion without an apparent reduction in contact angle. The as-prepared composite TiO 2 @fabric demonstrated good anti-UV ability. Moreover, the composite fabric demonstrated highly efficient oil–water separation due to its extreme wettability contrast (superhydrophobicity/superoleophilicity). We expect that this facile process can be readily and widely adopted for the design of multifunctional fabrics for excellent anti-UV, effective self-cleaning, efficient oil–water separation, and microfluidic management applications.
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              Robust fluorine-free superhydrophobic PDMS–ormosil@fabrics for highly effective self-cleaning and efficient oil–water separation

              Robust superhydrophobic fabrics constructed by a novel environmentally friendly coating strategy demonstrate multifunctional applications for effective anti-fouling, self-cleaning and versatile oil/water separation. Superhydrophobic cotton fabrics were prepared via a facile and environmentally friendly strategy to deposit an organically modified silica aerogel (ormosil) thin film onto the fabrics first, followed by polydimethylsiloxane (PDMS) topcoating. The PDMS–ormosil coating displayed a uniform 3D fractal-like structure with numerous loose micro-scale pores, while the PDMS layer increased the binding strength of the hierarchical ormosil film to form a highly robust porous network on the fibers. In comparison with hydrophilic cotton fabrics, the modified cotton fabric exhibited a highly superhydrophobic activity with a water contact angle higher than 160° and a sliding angle lower than 10°. The as-constructed PDMS–ormosil@fabrics are able to withstand 100 cycles of abrasion and 5 cycles of accelerated machine wash without an apparent decrease of superhydrophobicity. In addition, the superhydrophobic cotton fabrics are very stable in strongly acidic and alkaline solutions. Furthermore, the superhydrophobic coating has no or negligible adverse effect on the important textile physical properties of the cotton fabric, such as the strength, air permeability, and flexibility. The composite super-antiwetting fabrics have demonstrated excellent anti-fouling, self-cleaning ability and are highly efficient in oil–water separation for various oil–water mixtures. This facile synthesis technique has the advantages of scalable fabrication of multifunctional fabrics for potential applications in self-cleaning and versatile water–oil separation.
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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                07 January 2020
                21 January 2020
                : 5
                : 2
                : 986-994
                Affiliations
                []National & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Health, School of Textile & Clothing, Nantong University , Nantong 226019, P. R. China
                []College of Textile and Clothing Engineering, Soochow University , Suzhou 215123, P. R. China
                [§ ]Institute of Applied Physics and Materials Engineering, University of Macau , Macau 999078, P. R. China
                []National Engineering Research Center of Chemical Fertilizer Catalyst (NERC−CFC), College of Chemical Engineering, Fuzhou University , Fuzhou 350116, P. R. China
                Author notes
                Article
                10.1021/acsomega.9b03912
                6977067
                31984254
                29b06a1d-5aee-4135-af0a-f568973411e3
                Copyright © 2020 American Chemical Society

                This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.

                History
                : 15 November 2019
                : 23 December 2019
                Categories
                Mini-Review
                Custom metadata
                ao9b03912
                ao9b03912

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