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      Surface Modification of Cotton Fabric Using TiO 2 Nanoparticles for Self-Cleaning, Oil–Water Separation, Antistain, Anti-Water Absorption, and Antibacterial Properties

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      ACS Omega
      American Chemical Society

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          Abstract

          Superhydrophobicity is of interest for practical applications such as water repellency, self-cleaning, stain resistance, antibacterial properties, and oil–water separation. In this work, a superhydrophobic coating on cotton fabric is prepared by simple immersion in TiO 2 nanoparticles and perfluorodecyltriethoxysilane solution. Its antiwetting properties, surface morphology, and functionality are characterized. The cotton fabric shows superhydrophobicity with a water static contact angle of 169.3 ± 2.1° and tilt angle of 6.3 ± 2.0°. The coating is also characterized by performing stability tests, and it shows excellent mechanical durability, chemical stability, and thermal stability. Additionally, the water droplet dynamic on the coated surface is also studied. The coated cotton fabric exhibits excellent self-cleaning, stain resistance, rust stain resistance, anti-water absorption, and antibacterial properties. It can also be used in oil–water separation with a high separation efficiency and excellent reusability.

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          Robust and durable superhydrophobic cotton fabrics for oil/water separation.

          By introducing the incorporation of polyaniline and fluorinated alkyl silane to the cotton fabric via a facile vapor phase deposition process, the fabric surface possessed superhydrophobicity with the water contact angle of 156° and superoleophilicity with the oil contact angle of 0°. The as-prepared fabric can be applied as effective materials for the separation of water and oil mixture with separation efficiency as high as 97.8%. Compared with other materials for oil/water separation, the reported process was simple, time-saving, and repeatable for at least 30 times. Moreover, the obtained fabric kept stable superhydrophobicity and high separation efficiency under extreme environment conditions of high temperature, high humidity, strong acidic or alkaline solutions, and mechanical forces. Therefore, this reported fabric has the advantages of scalable fabrication, high separation efficiency, stable recyclability, and excellent durability, exhibiting the strong potential for industrial production.
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            Robust superhydrophobic TiO2@fabrics for UV shielding, self-cleaning and oil–water separation

            Multifunctional robust TiO 2 @fabrics with special wettability demonstrated potential applications for excellent UV shielding, effective self-cleaning, efficient oil–water separation and microfluidic management. Inspired by the surface geometry and composition of the lotus leaf with its self-cleaning behavior, in this work, a TiO 2 @fabric composite was prepared via a facile strategy for preparing marigold flower-like hierarchical TiO 2 particles through a one-pot hydrothermal reaction on a cotton fabric surface. In addition, a robust superhydrophobic TiO 2 @fabric was further constructed by fluoroalkylsilane modification as a versatile platform for UV shielding, self-cleaning and oil–water separation. The results showed TiO 2 particles were uniformly distributed on the fibre surface with a high coating density. In comparison with hydrophobic cotton fabric, the TiO 2 @fabric exhibited a high superhydrophobic activity with a contact angle of ∼160° and a sliding angle lower than 10°. The robust superhydrophobic fabric had high stability against repeated abrasion without an apparent reduction in contact angle. The as-prepared composite TiO 2 @fabric demonstrated good anti-UV ability. Moreover, the composite fabric demonstrated highly efficient oil–water separation due to its extreme wettability contrast (superhydrophobicity/superoleophilicity). We expect that this facile process can be readily and widely adopted for the design of multifunctional fabrics for excellent anti-UV, effective self-cleaning, efficient oil–water separation, and microfluidic management applications.
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              Superhydrophobic conductive textiles with antibacterial property by coating fibers with silver nanoparticles

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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                31 March 2020
                14 April 2020
                : 5
                : 14
                : 7850-7860
                Affiliations
                [1]Department of Chemical Engineering, Indian Institute of Technology (Indian School of Mines) , Dhanbad 826004, Jharkhand, India
                Author notes
                Article
                10.1021/acsomega.9b04067
                7160840
                32309694
                d10bb088-4eeb-4dec-b5e9-890c4630960a
                Copyright © 2020 American Chemical Society

                This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.

                History
                : 29 November 2019
                : 20 March 2020
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                ao9b04067

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