Direct surface coating of high voltage LiCoO ₂ cathode with P(VDF-HFP) based gel polymer electrolyte†

Abstract

For high-voltage cycling of lithium-ion batteries, a gel polymer Li-ion conductor layer, P(VDF-HFP)/LiTFSI (PHL) with high electrochemical stability has been coated on the surfaces of as-formed LiCoO ₂ (LCO) cathodes by a solution-casting technique at low temperature. An LCO cathode coated with around 3 μm thickness of the PHL ultrathin membrane, retains 88.4% of its original capacity (184.3 mA h g ⁻¹) after 200 cycles in the 3.0–4.6 V range with a standard carbonate electrolyte, while the non-coated one retains only 80.4% of its original capacity (171.5 mA h g ⁻¹). The reason for the better electrochemical behaviors and high-voltage cycling is related to the distinctive characteristics of the PHL coating layer that is compact, has highly-continuous surface coverage and penetrates the bulk of LCO, forming an integrated electrode. The PHL coating layer plays the role of an ion-conductive protection barrier to inhibit side reactions between the charged LCO surface and electrolyte, reduces the dissolution of cobalt ions and maintains the structural stability of LCO. Further, the PHL coated LCO cathode is well preserved, compared to the uncoated one which is severely cracked after 200 cycles at a charging cut-off voltage of 4.6 V.

Abstract

For high-voltage cycling of lithium-ion batteries, a Li-ion conductor layer, P(VDF-HFP)/LiTFSI with high electrochemical stability has been coated on the surfaces of as-formed LiCoO ₂ cathodes by a solution casting technique at low temperature.