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      Solar‐Powered High‐Performance Lignin‐Wood Evaporator for Solar Steam Generation

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          Abstract

          Recent research on wood‐based solar evaporators has made great progress and significant breakthroughs have been made in using lignin as a photothermal material; however, the intensity change mechanism regarding the conjugate structure of lignin is almost never mentioned. This study innovatively proposes a mechanism to explain the changes in conjugate intensity that occur before and after lignin dissolution and fabricates a lignin/wood‐based solar evaporator (LWE) using an all‐wood‐based material that is salt‐tolerant and has long‐term serviceability. Lignin in the evaporator serves not only as a photothermal material for converting light energy into heat energy but also as a reinforcement for the evaporator's structural strength. Adding lignin changes the original structure of balsa wood, increasing the proportion of intermediate water in the LWE, thereby lowering the enthalpy of water evaporation. The optimized LWE with an enhanced desalination capability, dye removal property, and high stability exhibits full‐spectrum solar absorption of about 83.6%, a photothermal conversion efficiency of 91.74%, and an evaporation efficiency of 1.93 kg m −2 h −1, which surpasses most wood‐based evaporators. This study demonstrates that all‐wood‐based materials can be used to prepare evaporators with excellent performance, providing a new approach to address freshwater depletion.

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          Most cited references45

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          3D self-assembly of aluminium nanoparticles for plasmon-enhanced solar desalination

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            Highly efficient solar vapour generation via hierarchically nanostructured gels

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              Graphene oxide-based efficient and scalable solar desalination under one sun with a confined 2D water path

              Direct solar desalination, which produces desalinated water directly using solar energy with minimum carbon footprint, is considered a promising technology to address the global water scarcity. Here, we report a solar desalination device, with efficient two-dimensional water supply and suppressed thermal loss, which can enable an efficient (80% under one-sun illumination) and effective (four orders salinity decrement) solar desalination. The energy transfer efficiency of this foldable graphene oxide film-based device fabricated by a scalable process is independent of water quantity and can be achieved without optical or thermal supporting systems, therefore significantly improving the scalability and feasibility of this technology toward a complementary portable and personalized water solution. Because it is able to produce desalinated water directly using solar energy with minimum carbon footprint, solar steam generation and desalination is considered one of the most important technologies to address the increasingly pressing global water scarcity. Despite tremendous progress in the past few years, efficient solar steam generation and desalination can only be achieved for rather limited water quantity with the assistance of concentrators and thermal insulation, not feasible for large-scale applications. The fundamental paradox is that the conventional design of direct absorber−bulk water contact ensures efficient energy transfer and water supply but also has intrinsic thermal loss through bulk water. Here, enabled by a confined 2D water path, we report an efficient (80% under one-sun illumination) and effective (four orders salinity decrement) solar desalination device. More strikingly, because of minimized heat loss, high efficiency of solar desalination is independent of the water quantity and can be maintained without thermal insulation of the container. A foldable graphene oxide film, fabricated by a scalable process, serves as efficient solar absorbers (>94%), vapor channels, and thermal insulators. With unique structure designs fabricated by scalable processes and high and stable efficiency achieved under normal solar illumination independent of water quantity without any supporting systems, our device represents a concrete step for solar desalination to emerge as a complementary portable and personalized clean water solution.
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                Author and article information

                Contributors
                Journal
                Advanced Functional Materials
                Adv Funct Materials
                Wiley
                1616-301X
                1616-3028
                October 2023
                August 30 2023
                October 2023
                : 33
                : 43
                Affiliations
                [1 ] Co‐Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and Materials Joint International Research Lab of Lignocellulosic Functional Materials College of Material Science and Engineering Nanjing Forestry University Nanjing 210037 China
                [2 ] Jiangsu Co‐Innovation Center of Efficient Processing and Utilization of Forest Resources Nanjing Forestry University Nanjing 210037 China
                [3 ] College of Biology and Environment Nanjing Forestry University Nanjing 210037 China
                [4 ] Jiangsu Co‐Innovation Center of Efficient Processing and Utilization of Forest Resources College of Chemical Engineering Nanjing Forestry University Nanjing 210037 China
                [5 ] Chemical Engineering Department New Brunswick University Fredericton NB E3B 5A3 Canada
                Article
                10.1002/adfm.202306947
                0537a019-9fad-447b-9795-7eef85f2d179
                © 2023

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