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      Advances on Sb2Se3 Solar Cells Fabricated by Physical Vapor Deposition Techniques

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      Solar
      MDPI AG

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          Abstract

          Sb2Se3, as an earth-abundant and low-toxic material, has emerged as one of the most interesting absorbers for clean renewable power generation technologies. Due to its optical properties, especially bandgap and absorption coefficient, the number of papers on Sb2Se3-based solar cells has been constantly increasing in the last ten years, and its power conversion efficiency has raised from 1% in 2014 to 10.57% in 2022. In this review, different Sb2Se3 solar cells’ fabrication technologies based on physical vapor deposition are described and correlated to the texture coefficient (ribbon orientation). Moreover, recent research works of the most promising solar cell configurations with different electron-transporting layers and hole-transporting layers are analyzed with a special emphasis on photovoltaic performances. Furthermore, different Sb2Se3 doping techniques are discussed. All these aspects are considered as new strategies to overcome the Sb2Se3 solar cell’s actual limitations.

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          Detailed Balance Limit of Efficiency of p-n Junction Solar Cells

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            Thin-film Sb2Se3 photovoltaics with oriented one-dimensional ribbons and benign grain boundaries

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              9.2%-efficient core-shell structured antimony selenide nanorod array solar cells

              Antimony selenide (Sb2Se3) has a one-dimensional (1D) crystal structure comprising of covalently bonded (Sb4Se6) n ribbons stacking together through van der Waals force. This special structure results in anisotropic optical and electrical properties. Currently, the photovoltaic device performance is dominated by the grain orientation in the Sb2Se3 thin film absorbers. Effective approaches to enhance the carrier collection and overall power-conversion efficiency are urgently required. Here, we report the construction of Sb2Se3 solar cells with high-quality Sb2Se3 nanorod arrays absorber along the [001] direction, which is beneficial for sun-light absorption and charge carrier extraction. An efficiency of 9.2%, which is the highest value reported so far for this type of solar cells, is achieved by junction interface engineering. Our cell design provides an approach to further improve the efficiency of Sb2Se3-based solar cells.
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                Author and article information

                Contributors
                (View ORCID Profile)
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                Journal
                SBSOCZ
                Solar
                Solar
                MDPI AG
                2673-9941
                December 2023
                October 12 2023
                : 3
                : 4
                : 566-595
                Article
                10.3390/solar3040031
                5d4a3c09-bbd9-4b40-bbc9-95b90b8f8358
                © 2023

                https://creativecommons.org/licenses/by/4.0/

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