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      Siloles in optoelectronic devices

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          Abstract

          This review covers the electronic properties of silole-based organic semiconductors and the newest developments in the field of silole-based OLEDs and OPVs.

          Abstract

          Typical optoelectronic devices are transducers used to realize energy conversion between light and electric current. Optoelectronic devices have a wide variety of applications as diverse as e.g. light-emitting diodes, photovoltaic technology, photoconductive cells, laser diodes, photoemissive camera tubes, optocouplers etc. Their versatile utility necessitates a cost-efficient industrial-scale production. The last decade has witnessed a rapid development and great improvement in the efficiency of optoelectronic devices and revealed their evergrowing need in new organic semiconducting materials that are at the heart of such devices. This review article covers the electronic properties of silole-based organic semiconductors including tetraarylsilole, spirosilole, fused silole molecules and polymers, recently applied in OLEDs and OPVs, and their optoelectronic device performances. And an outlook on the future investigations of silole-based materials is offered.

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          Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole

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            Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells.

            A new polymer donor (PBDB-T-SF) and a new small molecule acceptor (IT-4F) for fullerene-free organic solar cells (OSCs) were designed and synthesized. The influences of fluorination on the absorption spectra, molecular energy levels, and charge mobilities of the donor and acceptor were systematically studied. The PBDB-T-SF:IT-4F-based OSC device showed a record high efficiency of 13.1%, and an efficiency of over 12% can be obtained with a thickness of 100-200 nm, suggesting the promise of fullerene-free OSCs in practical applications.
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              25th anniversary article: a decade of organic/polymeric photovoltaic research.

              Organic photovoltaic (OPV) technology has been developed and improved from a fancy concept with less than 1% power conversion efficiency (PCE) to over 10% PCE, particularly through the efforts in the last decade. The significant progress is the result of multidisciplinary research ranging from chemistry, material science, physics, and engineering. These efforts include the design and synthesis of novel compounds, understanding and controlling the film morphology, elucidating the device mechanisms, developing new device architectures, and improving large-scale manufacture. All of these achievements catalyzed the rapid growth of the OPV technology. This review article takes a retrospective look at the research and development of OPV, and focuses on recent advances of solution-processed materials and devices during the last decade, particular the polymer version of the materials and devices. The work in this field is exciting and OPV technology is a promising candidate for future thin film solar cells. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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                Author and article information

                Contributors
                Journal
                JMCCCX
                Journal of Materials Chemistry C
                J. Mater. Chem. C
                Royal Society of Chemistry (RSC)
                2050-7526
                2050-7534
                2017
                2017
                : 5
                : 30
                : 7375-7389
                Affiliations
                [1 ]Guangdong Innovative Research Team
                [2 ]State Key Laboratory of Luminescent Materials and Devices
                [3 ]South China University of Technology
                [4 ]Guangzhou 510640
                [5 ]China
                Article
                10.1039/C7TC02511D
                b46313df-b15b-47a3-927e-49ca0f216b55
                © 2017
                History

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