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      Boosting Zinc Electrode Reversibility in Aqueous Electrolytes by Using Low‐Cost Antisolvents

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          Is Open Access

          Double-slit photoelectron interference in strong-field ionization of the neon dimer

          Wave-particle duality is an inherent peculiarity of the quantum world. The double-slit experiment has been frequently used for understanding different aspects of this fundamental concept. The occurrence of interference rests on the lack of which-way information and on the absence of decoherence mechanisms, which could scramble the wave fronts. Here, we report on the observation of two-center interference in the molecular-frame photoelectron momentum distribution upon ionization of the neon dimer by a strong laser field. Postselection of ions, which are measured in coincidence with electrons, allows choosing the symmetry of the residual ion, leading to observation of both, gerade and ungerade, types of interference.
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            Highly reversible zinc metal anode for aqueous batteries

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              "Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries.

              Lithium-ion batteries raise safety, environmental, and cost concerns, which mostly arise from their nonaqueous electrolytes. The use of aqueous alternatives is limited by their narrow electrochemical stability window (1.23 volts), which sets an intrinsic limit on the practical voltage and energy output. We report a highly concentrated aqueous electrolyte whose window was expanded to ~3.0 volts with the formation of an electrode-electrolyte interphase. A full lithium-ion battery of 2.3 volts using such an aqueous electrolyte was demonstrated to cycle up to 1000 times, with nearly 100% coulombic efficiency at both low (0.15 coulomb) and high (4.5 coulombs) discharge and charge rates.
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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley
                1433-7851
                1521-3773
                March 22 2021
                February 24 2021
                March 22 2021
                : 60
                : 13
                : 7366-7375
                Affiliations
                [1 ]School of Chemical Engineering & Advanced Materials The University of Adelaide Adelaide SA 5005 Australia
                [2 ]Institute for Superconducting and Electronic Materials Australian Institute for Innovative Materials University of Wollongong Wollongong NSW 2522 Australia
                Article
                10.1002/anie.202016531
                33440043
                fd0c34c2-056b-408b-adf6-91a4ce10360a
                © 2021

                http://onlinelibrary.wiley.com/termsAndConditions#am

                http://onlinelibrary.wiley.com/termsAndConditions#vor

                http://doi.wiley.com/10.1002/tdm_license_1.1

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