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      NMR reveals the surface functionalisation of Ti3C2 MXene

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          Abstract

          1H and 19F NMR experiments have identified and quantified the internal surface terminations of Ti3C2Tx MXene.

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          Intercalation and delamination of layered carbides and carbonitrides.

          Olha Mashtalir, Michael Naguib, Vadym Mochalin … (2013)
          Intercalation and delamination of two-dimensional solids in many cases is a requisite step for exploiting their unique properties. Herein we report on the intercalation of two-dimensional Ti3C2, Ti3CN and TiNbC-so called MXenes. Intercalation of hydrazine, and its co-intercalation with N,N-dimethylformamide, resulted in increases of the c-lattice parameters of surface functionalized f-Ti3C2, from 19.5 to 25.48 and 26.8 Å, respectively. Urea is also intercalated into f-Ti3C2. Molecular dynamics simulations suggest that a hydrazine monolayer intercalates between f-Ti3C2 layers. Hydrazine is also intercalated into f-Ti3CN and f-TiNbC. When dimethyl sulphoxide is intercalated into f-Ti3C2, followed by sonication in water, the f-Ti3C2 is delaminated forming a stable colloidal solution that is in turn filtered to produce MXene 'paper'. The latter shows excellent Li-ion capacity at extremely high charging rates.
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            X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)

            Joseph Halim, Kevin Cook, Michael Naguib … (2016)
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              Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide.

              Qiuming Peng, Jianxin Guo, Qingrui Zhang … (2014)
              The functional groups and site interactions on the surfaces of two-dimensional (2D) layered titanium carbide can be tailored to attain some extraordinary physical properties. Herein a 2D alk-MXene (Ti3C2(OH/ONa)(x)F(2-x)) material, prepared by chemical exfoliation followed by alkalization intercalation, exhibits preferential Pb(II) sorption behavior when competing cations (Ca(II)/Mg(II)) coexisted at high levels. Kinetic tests show that the sorption equilibrium is achieved in as short a time as 120 s. Attractively, the alk-MXene presents efficient Pb(II) uptake performance with the applied sorption capacities of 4500 kg water per alk-MXene, and the effluent Pb(II) contents are below the drinking water standard recommended by the World Health Organization (10 μg/L). Experimental and computational studies suggest that the sorption behavior is related to the hydroxyl groups in activated Ti sites, where Pb(II) ion exchange is facilitated by the formation of a hexagonal potential trap.
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                Author and article information

                Journal
                Journal ID (publisher-id): PPCPFQ
                Title: Phys. Chem. Chem. Phys.
                Abbreviated Title: Phys. Chem. Chem. Phys.
                Publisher: Royal Society of Chemistry (RSC)
                ISSN (Print): 1463-9076
                ISSN (Electronic): 1463-9084
                Publication date Created: 2016
                Publication date (Print): 2016
                Volume: 18
                Issue: 7
                Pages: 5099-5102
                Article
                DOI: 10.1039/C6CP00330C
                PubMed ID: 26818187
                SO-VID: fc0615fa-9e3c-4175-91f6-e74d5289cd7d
                Copyright © © 2016
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