Ultrasonic desulfurization of amphiphilic magnetic-Janus nanosheets in oil-water mixture system

Highlights

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  Changing Fenton reagent from uniparental to amphiphilic by Amphiphilic Janus material.

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  Supporting the Production of Hydroxyl Radicals by Ultrasound.

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  Improving the oxidative desulfurization ability and reusability of Fenton reagent.

Abstract

Fe ₃O ₄ was obtained by reacting FeCl ₂ and FeCl ₃ with polyethylene glycol, and labeled onto a amphiphilic Janus nanosheet. It was confirmed by infrared spectroscopy, SEM, AFM and EDS that the Fe ₃O ₄ nanoparticles changed from hydrophilic to amphiphilic. The oxidative desulfurization performance of amphiphilic iron oxide was studied. Results showed that the Janus nanosheets labeled with Fe ₃O ₄ could significantly improve the removal rate of thiophene sulfide in simulated oil synergistically with ultrasonic waves, and the desulfurization rate could reach 100%. Further, the effect of ultrasound on the sensing ability of the oil–water interface was studied and the ultrasonic attenuation coefficient was calculated. In addition to the desulfurization mechanism of Fe ₃O ₄, it was found that although the ultrasonic attenuation coefficient of the amphiphilic nanosheets was high, the number of hydroxyl radicals determined the desulfurization efficiency. The amphiphilic Fe ions were more favorable for the formation of hydroxyl radicals than the single hydrophilic ones.