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      On subthreshold ionization of helium droplets, ejection of He(+), and the role of anions.

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          Abstract

          The mechanism of ionization of helium droplets has been investigated in numerous reports but one observation has not found a satisfactory explanation: How are He(+) ions formed and ejected from undoped droplets at electron energies below the ionization threshold of the free atom? Does this path exist at all? A measurement of the ion yields of He(+) and He2(+) as a function of electron energy, electron emission current, and droplet size reveals that metastable He*(-) anions play a crucial role in the formation of free He(+) at subthreshold energies. The proposed model is testable.

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          Author and article information

          Journal
          Phys Chem Chem Phys
          Physical chemistry chemical physics : PCCP
          Royal Society of Chemistry (RSC)
          1463-9084
          1463-9076
          Nov 07 2014
          : 16
          : 41
          Affiliations
          [1 ] Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25, A-6020 Innsbruck, Austria. paul.scheier@uibk.ac.at.
          Article
          10.1039/c4cp03236e
          25230760
          ed4a1027-92bd-4dce-bfde-a4ad1ce59cef
          History

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