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      An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane

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      Journal of the American Chemical Society
      American Chemical Society (ACS)

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          Abstract

          Nickel hydride with a diphosphinite-based ligand catalyzes the highly efficient reduction of CO(2) with catecholborane, and the hydrolysis of the resulting methoxyboryl species produces CH(3)OH in good yield. The mechanism involves a nickel formate, formaldehyde, and a nickel methoxide as different reduced stages for CO(2). The reaction may also be catalyzed by an air-stable nickel formate.

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          Author and article information

          Journal
          Journal of the American Chemical Society
          J. Am. Chem. Soc.
          American Chemical Society (ACS)
          0002-7863
          1520-5126
          July 07 2010
          July 07 2010
          : 132
          : 26
          : 8872-8873
          Article
          10.1021/ja103982t
          20540579
          ed2df3d1-8c56-4cda-96fd-c348b0e893a2
          © 2010
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