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      Fast fabrication of bismuth oxyiodide/carbon‐nanofibers composites for efficient anti‐proliferation of liver and breast cancer cells

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          Abstract

          Semiconductor synthesis and applications are of increasing interest worldwide. A simple non‐autoclave method was developed to synthesize bismuth oxyiodide (BiOI) nanoparticles and nanocomposites of BiOI/carbon nanofibers (CNFs) in propylene glycol as a solvent. The as‐prepared BiOI and its CNFs‐composites were characterized by powder X‐ray diffraction (XRD), scanning electron microscopy‐energy X‐ray‐dispersive spectroscopy (SEM‐EDX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT‐IR), Nitrogen adsorption‐desorption‐isotherm, and UV‐vis diffuse reflectance spectra. The XRD pattern confirmed that BiOI nanomaterial was prepared successfully by the developed method. SEM and TEM analysis revealed the BiOI in its pure and composites forms possessing rose‐like nanosheets built with BiOI nanoparticles. The addition of CNFs to the BiOI in increasing mass percentage enhanced the optical properties of the BiOI‐semiconductor. The obtained results confirmed that the short‐time refluxing method prepared BiOI and BiOI/CNFs composites successfully, with the advantage of eliminating the time and energy‐consuming step of autoclave digestion. Nevertheless, the nanomaterial‘s anticancer activity was revealed when tested against breast and liver cancer cell lines and measured at 540 nm.

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          Most cited references54

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          Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)

          Gas adsorption is an important tool for the characterisation of porous solids and fine powders. Major advances in recent years have made it necessary to update the 1985 IUPAC manual on Reporting Physisorption Data for Gas/Solid Systems. The aims of the present document are to clarify and standardise the presentation, nomenclature and methodology associated with the application of physisorption for surface area assessment and pore size analysis and to draw attention to remaining problems in the interpretation of physisorption data.
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            Advanced nanoarchitectures for solar photocatalytic applications.

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              Engineering BiOX (X = Cl, Br, I) nanostructures for highly efficient photocatalytic applications.

              Heterogeneous photocatalysis that employs photo-excited semiconductor materials to reduce water and oxidize toxic pollutants upon solar light irradiation holds great prospects for renewable energy substitutes and environmental protection. To utilize solar light effectively, the quest for highly active photocatalysts working under visible light has always been the research focus. Layered BiOX (X = Cl, Br, I) are a kind of newly exploited efficient photocatalysts, and their light response can be tuned from UV to visible light range. The properties of semiconductors are dependent on their morphologies and compositions as well as structures, and this also offers the guidelines for design of highly-efficient photocatalysts. In this review, recent advances and emerging strategies in tailoring BiOX (X = Cl, Br, I) nanostructures to boost their photocatalytic properties are surveyed.
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                Author and article information

                Journal
                Zeitschrift für anorganische und allgemeine Chemie
                Zeitschrift anorg allge chemie
                0044-2313
                1521-3749
                October 12 2021
                August 23 2021
                October 12 2021
                : 647
                : 19
                : 1921-1929
                Affiliations
                [1 ] Imam Mohammad Ibn Saud Islamic University (IMSIU) College of Science, Chemistry Department P.O. Box 90905 Riyadh 11623 KSA
                [2 ] Industrial research and consultancy center (IRCC) Khartoum North Sudan
                [3 ] Sudan University of Science and Technology (SUST) College of Science, Chemistry Department P.O. Box 407 Khartoum Sudan
                [4 ] Imam Mohammad Ibn Saud Islamic University (IMSIU) College of Science, Biology Department Riyadh Saudi Arabia
                [5 ] Department of Chemistry, Faculty of Education-Zabid Hodeidah University Hodeidah Yemen
                Article
                10.1002/zaac.202100205
                ebf12f97-2f92-4ba0-9c38-32002672dded
                © 2021

                http://onlinelibrary.wiley.com/termsAndConditions#vor

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