Incorporation of Lead Containing TV Tube Glass Waste in Aluminous Porcelain

Abstract

The aim of this work was to study the incorporation of lead containing TV tube glass waste as a method to provide alternative raw material for aluminous electrical porcelain. For this purpose, aluminous porcelain formulations containing up to 30 wt.% of TV tube glass waste as a replacement for traditional flux material (sodium feldspar) were pressed and fired in air at 1300 ºC using a fast-firing cycle (< 60 min). X-ray diffraction (XRD), scanning electron microscopy (SEM), linear shrinkage, apparent density, water absorption, and electrical resistivity have been carried out. The results indicated that the aluminous porcelain pieces containing up to 30 wt.% of TV tube glass waste rich in PbO with water absorption between 0.42 and 0.45% and volume electrical resistivity between 1.91 and 2.93 x 1011 Ω.cm have high potential to work as electrical insulator material. This use of lead containing TV tube glass waste can contribute greatly to reducing the environmental impacts related to it, and also save the sources of non-renewable raw materials used in the electrical porcelain sector.