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      Novel magnetically retrievable In 2O 3/MoS 2/Fe 3O 4 nanocomposite materials for enhanced photocatalytic performance

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          Abstract

          The current work involves synthesis of hybrid nanomaterial of In 2O 3/MoS 2/Fe 3O 4 and their applications as photocatalysts for disintegration of esomeprazole under visible light illumination. The data emerged from various analyses testified to the successful construction of the desired nano-scaled hybrid photocatalyst. Tauc plot gave the band gap of In 2O 3/MoS 2/Fe 3O 4 to be ~ 2.15 eV. Synergistic effects of the integrant components enabled efficacious photocatalytic performances of the nanocomposite. The nanohybrid photocatalyst In 2O 3/MoS 2/Fe 3O 4 showed photodecomposition up to ~ 92.92% within 50 min. The current work realizes its objective of constructing metal oxide based hybrid nano-photocatalyst supported on MoS 2 sheets for activity in the visible spectrum, which displayed remarkable capacity of disintegrating emerging persistent organic contaminants and are magnetically recoverable.

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          Emerging photoluminescence in monolayer MoS2.

          Andrea Splendiani, Liang Sun, Yuanbo Zhang … (2010)
          Novel physical phenomena can emerge in low-dimensional nanomaterials. Bulk MoS(2), a prototypical metal dichalcogenide, is an indirect bandgap semiconductor with negligible photoluminescence. When the MoS(2) crystal is thinned to monolayer, however, a strong photoluminescence emerges, indicating an indirect to direct bandgap transition in this d-electron system. This observation shows that quantum confinement in layered d-electron materials like MoS(2) provides new opportunities for engineering the electronic structure of matter at the nanoscale.
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            The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets.

            Manish Chhowalla, Hyeon Shin, Goki Eda … (2013)
            Ultrathin two-dimensional nanosheets of layered transition metal dichalcogenides (TMDs) are fundamentally and technologically intriguing. In contrast to the graphene sheet, they are chemically versatile. Mono- or few-layered TMDs - obtained either through exfoliation of bulk materials or bottom-up syntheses - are direct-gap semiconductors whose bandgap energy, as well as carrier type (n- or p-type), varies between compounds depending on their composition, structure and dimensionality. In this Review, we describe how the tunable electronic structure of TMDs makes them attractive for a variety of applications. They have been investigated as chemically active electrocatalysts for hydrogen evolution and hydrosulfurization, as well as electrically active materials in opto-electronics. Their morphologies and properties are also useful for energy storage applications such as electrodes for Li-ion batteries and supercapacitors.
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              Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni

              Mark Biesinger, Brad P. Payne, Andrew Grosvenor … (2011)
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                Author and article information

                Contributors
                Md. Ahmaruzzaman: mda2002@gmail.com
                Journal
                Journal ID (nlm-ta): Sci Rep
                Journal ID (iso-abbrev): Sci Rep
                Title: Scientific Reports
                Publisher: Nature Publishing Group UK (London )
                ISSN (Electronic): 2045-2322
                Publication date (Electronic): 18 March 2021
                Publication date PMC-release: 18 March 2021
                Publication date Collection: 2021
                Volume: 11
                Electronic Location Identifier: 6379
                Affiliations
                GRID grid.444720.1, Department of Chemistry, , National Institute of Technology Silchar, ; Silchar, Assam 788010 India
                Article
                Publisher ID: 85532
                DOI: 10.1038/s41598-021-85532-8
                PMC ID: 7973746
                SO-VID: e952a536-3479-4e73-ad6d-0d27f3747eef
                Copyright © © The Author(s) 2021
                License:

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

                History
                Date received : 10 September 2020
                Date accepted : 2 March 2021
                Funding
                Funded by: No Funding
                Categories
                Subject: Article
                Custom metadata
                issue-copyright-statement © The Author(s) 2021

                ScienceOpen disciplines: Uncategorized
                Keywords: pollution remediation,nanoscience and technology,nanoscale materials,magnetic properties and materials
                Data availability:
                ScienceOpen disciplines: Uncategorized
                Keywords: pollution remediation, nanoscience and technology, nanoscale materials, magnetic properties and materials

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