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      Universal quinone electrodes for long cycle life aqueous rechargeable batteries

      Author(s): , , , , , ,
      Publication date Created:
      Publication date (Print):
      Journal: Nature Materials
      Publisher: Springer Nature

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          Abstract

          Aqueous rechargeable batteries are promising for grid storage and electric vehicles, but they suffer from poor cycle life due to anode instability. Exploiting stable ion-coordination charge storage and chemical inertness towards aqueous electrolytes, quinones are now reported as stable anodes.

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          "Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries.

          Liumin Suo, Oleg Borodin, Tao Gao … (2015)
          Lithium-ion batteries raise safety, environmental, and cost concerns, which mostly arise from their nonaqueous electrolytes. The use of aqueous alternatives is limited by their narrow electrochemical stability window (1.23 volts), which sets an intrinsic limit on the practical voltage and energy output. We report a highly concentrated aqueous electrolyte whose window was expanded to ~3.0 volts with the formation of an electrode-electrolyte interphase. A full lithium-ion battery of 2.3 volts using such an aqueous electrolyte was demonstrated to cycle up to 1000 times, with nearly 100% coulombic efficiency at both low (0.15 coulomb) and high (4.5 coulombs) discharge and charge rates.
          Article 0 comments Cited 991 times – based on 0 reviews     Review now
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            Reversible aqueous zinc/manganese oxide energy storage from conversion reactions

            Huilin Pan, Yuyan Shao, Pengfei Yan … (2016)
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              A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

              Dipan Kundu, Brian Adams, Victor Duffort … (2016)
              Article 0 comments Cited 916 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Title: Nature Materials
                Abbreviated Title: Nat Mater
                Publisher: Springer Nature
                ISSN (Print): 1476-1122
                ISSN (Electronic): 1476-4660
                Publication date Created: June 19 2017
                Publication date (Print): June 19 2017
                Volume:
                Issue:
                Article
                DOI: 10.1038/nmat4919
                PubMed ID: 28628121
                SO-VID: e85e3e7e-7020-4ca3-a46c-1f20f6ce2e00
                Copyright © © 2017
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