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      Metal–Organic Frameworks and Their Derived Functional Materials for Supercapacitor Electrode Application

      1 , 2 , 2
      Advanced Energy and Sustainability Research
      Wiley

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          Abstract

          Metal–organic frameworks (MOFs) are deemed an attractive type of active material during electrochemical reaction processes because of their unique compositional and structural superiority, as well as the dual role as both templates and precursors to derive a large variety of functional materials for energy conversation and storage. Herein, reviewing the recent advances of MOFs and their derived functional materials as electrode materials in supercapacitors, which are classified into pristine MOFs, MOF composites, and MOF‐derived functional materials, is focused on. Their synthetic routes and modification strategies are summarized and the relationship between the diversity of the architectures and compositions of MOF‐based materials and their electrochemical performance is discussed. In addition, the challenges and opportunities on future research and extensive applications of MOFs and their derived functional materials are offered.

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          The chemistry and applications of metal-organic frameworks.

          Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.
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            Carbon materials for chemical capacitive energy storage.

            Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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              Conductive MOF electrodes for stable supercapacitors with high areal capacitance

              Using MOFs as active electrodes in electrochemical double layer capacitors has so far proved difficult. An electrically conductive MOF used as an electrode is now shown to exhibit electrochemical performance similar to most carbon-based materials.
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                Author and article information

                Contributors
                Journal
                Advanced Energy and Sustainability Research
                Adv Energy and Sustain Res
                Wiley
                2699-9412
                2699-9412
                July 2021
                May 05 2021
                July 2021
                : 2
                : 7
                Affiliations
                [1 ] Key Laboratory of State Forestry Administration for Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China Southwest Forestry University Kunming 650000 P. R. China
                [2 ] Alan G. MacDiarmid Institute College of Chemistry Jilin University Changchun 130012 P. R. China
                Article
                10.1002/aesr.202100024
                e3a586ec-9eec-4831-81c2-46c1af5919e7
                © 2021

                http://creativecommons.org/licenses/by/4.0/

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