Recent trends in organic coating based on biopolymers and biomass for controlled and slow release fertilizers

With the exponential growth of the global population, the agricultural sector is bound to use ever larger quantities of fertilizers to augment the food supply, which consequently increases food production costs. Urea, when applied to crops is vulnerable to losses from volatilization and leaching. Current methods also reduce nitrogen use efficiency (NUE) by plants which limits crop yields and, moreover, contributes towards environmental pollution in terms of hazardous gaseous emissions and water eutrophication. An approach that offsets this pollution while also enhancing NUE is the use of controlled release urea (CRU) for which several methods and materials have been reported. The physical intromission of urea granules in an appropriate coating material is one such technique that produces controlled release coated urea (CRCU). The development of CRCU is a green technology that not only reduces nitrogen loss caused by volatilization and leaching, but also alters the kinetics of nitrogen release, which, in turn, provides nutrients to plants at a pace that is more compatible with their metabolic needs. This review covers the research quantum regarding the physical coating of original urea granules. Special emphasis is placed on the latest coating methods as well as release experiments and mechanisms with an integrated critical analyses followed by suggestions for future research.

Chitin is the second most common polymer after cellulose in earth, existing in the shells of crustaceans like crab and shrimp. Chitosan is a natural amino-polysaccharide derived from chitin, known as one of the most abundant organic materials in nature, it has been widely used in several applications due to its natural origin and exceptional properties such as biocompatibility, biodegradability, non-toxicity, and chelating of metal ions. Chitin and chitosan are characterized by deacetylation degree, one of the most important chemical characteristics that can influence the performance of chitosan in many applications. Chitosan is usually prepared by a thermochemical method, consuming time, energy and reagents. In this review, various methods of chitosan extraction will be approached and compared; the importance of a new method of ecological extraction will be emphasized. Moreover, in order to improve the chitosan functionality, and better control these physicochemical properties, several chemical modifications have been reported. These chemical modifications lead to a broad range of derivatives with a wide range of applications in many fields. Recent examples of the distinct applications, with particular emphasis on environmental applications, have been presented.