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      Synthesis of P1-(11-phenoxyundecyl)-P2-(2-acetamido-2-deoxy-3-O-α-D-rhamnopyranosyl-α-D-glucopyranosyl) diphosphate and P1-(11-phenoxyundecyl)-P2-(2-acetamido-2-deoxy-3-O-β-D-galactopyranosyl-α-D-galactopyranosyl) diphosphate for the investigation of biosynthesis of O-antigenic polysaccharides in Pseudomonas aeruginosa and Escherichia coli O104.

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          Abstract

          Two new phenoxyundecyl diphosphate sugars were synthesized for the first time: P1-(11-phenoxyundecyl)-P2- (2-acetamido-2-deoxy-3-O-α-D-rhamnopyranosyl-α-D-glucopyranosyl) diphosphate and P1-(11-phenoxyundecyl)-P2-(2-acetamido-2-deoxy-3-O-β-D-galactopyranosyl-α-D-galactopyranosyl) diphosphate to study the third step of biosynthesis of the repeating units of O-antigenic polysaccharides in Pseudomonas aeruginosa and E.coli O104 respectively.

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          Author and article information

          Journal
          Journal ID (iso-abbrev): Carbohydr Res
          Title: Carbohydrate research
          Publisher: Elsevier BV
          ISSN (Electronic): 1873-426X
          ISSN (Print): 0008-6215
          Publication date (Electronic): Dec 01 2017
          Volume: 453-454
          Affiliations
          [1 ] N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia.
          [2 ] N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia. Electronic address: utkinans@yahoo.com.
          [3 ] Department of Biomedical and Molecular Sciences, Queen's University, Kingston, Canada.
          Article
          Publisher Item ID: S0008-6215(17)30672-9
          DOI: 10.1016/j.carres.2017.10.016
          PubMed ID: 29107815
          SO-VID: e068df2b-af14-4617-8d44-f9092a9fcb0d
          History

          Keywords: P(1)-(11-phenoxyundecyl) -P(2)-(2-acetamido-2-deoxy-3-O-β-D-galactopyranosyl-α-D-galactopyranosyl) diphosphate,Pseudomonas aeruginosa,P(1)- (11-phenoxyundecyl) -P(2)-(2-acetamido-2-deoxy-3-O-α-D-rhamnopyranosyl-α-D-glucopyranosyl) diphosphate,Escherichia coli O104,Enterobacterial glycosyltransferases,Chemical synthesis
          Data availability:
          Keywords: P(1)-(11-phenoxyundecyl) -P(2)-(2-acetamido-2-deoxy-3-O-β-D-galactopyranosyl-α-D-galactopyranosyl) diphosphate, Pseudomonas aeruginosa, P(1)- (11-phenoxyundecyl) -P(2)-(2-acetamido-2-deoxy-3-O-α-D-rhamnopyranosyl-α-D-glucopyranosyl) diphosphate, Escherichia coli O104, Enterobacterial glycosyltransferases, Chemical synthesis

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