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      Spin-Orbit Physics Giving Rise to Novel Phases in Correlated Systems: Iridates and Related Materials

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          Abstract

          Recently, the effects of spin-orbit coupling (SOC) in correlated materials have become one of the most actively studied subjects in condensed matter physics, as correlations and SOC together can lead to the discovery of new phases. Among candidate materials, iridium oxides (iridates) have been an excellent playground to uncover such novel phenomena. In this review, we discuss recent progress in iridates and related materials, focusing on the basic concepts, relevant microscopic Hamiltonians, and unusual properties of iridates in perovskite- and honeycomb-based structures. Perspectives on SOC and correlation physics beyond iridates are also discussed.

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          Anyons in an exactly solved model and beyond

          A spin 1/2 system on a honeycomb lattice is studied. The interactions between nearest neighbors are of XX, YY or ZZ type, depending on the direction of the link; different types of interactions may differ in strength. The model is solved exactly by a reduction to free fermions in a static \(\mathbb{Z}_{2}\) gauge field. A phase diagram in the parameter space is obtained. One of the phases has an energy gap and carries excitations that are Abelian anyons. The other phase is gapless, but acquires a gap in the presence of magnetic field. In the latter case excitations are non-Abelian anyons whose braiding rules coincide with those of conformal blocks for the Ising model. We also consider a general theory of free fermions with a gapped spectrum, which is characterized by a spectral Chern number \(\nu\). The Abelian and non-Abelian phases of the original model correspond to \(\nu=0\) and \(\nu=\pm 1\), respectively. The anyonic properties of excitation depend on \(\nu\bmod 16\), whereas \(\nu\) itself governs edge thermal transport. The paper also provides mathematical background on anyons as well as an elementary theory of Chern number for quasidiagonal matrices.
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            Phase-sensitive observation of a spin-orbital Mott state in Sr2IrO4.

            Measurement of the quantum-mechanical phase in quantum matter provides the most direct manifestation of the underlying abstract physics. We used resonant x-ray scattering to probe the relative phases of constituent atomic orbitals in an electronic wave function, which uncovers the unconventional Mott insulating state induced by relativistic spin-orbit coupling in the layered 5d transition metal oxide Sr2IrO4. A selection rule based on intra-atomic interference effects establishes a complex spin-orbital state represented by an effective total angular momentum = 1/2 quantum number, the phase of which can lead to a quantum topological state of matter.
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              Direct evidence for dominant bond-directional interactions in a honeycomb lattice iridate Na2IrO3

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                Author and article information

                Journal
                2015-07-22
                Article
                10.1146/annurev-conmatphys-031115-011319
                1507.06323
                d9dccc44-3640-4490-95d8-f88e3780fddf

                http://arxiv.org/licenses/nonexclusive-distrib/1.0/

                History
                Custom metadata
                Annual Review of Condensed Matter Physics Vol. 7: 195-221 (2016)
                34 pages, 9 figures; To appear in Annual Reviews of Condensed Matter Physics
                cond-mat.str-el

                Condensed matter
                Condensed matter

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