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      Penta­carbonyl-2κ 5C- chlorido-1κ Cl-bis­[1(η 5)-cyclo­penta­dien­yl][μ 2-oxido(meth­yl)methyl­ene-1:2κ 2 O: C]tungsten(0)zirconium(IV)

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          Abstract

          The title compound, [ZrW(C 5H 5) 2(C 2H 3O)Cl(CO) 5] or [W(CO) 5C(CH 3)OZr(C 5H 5) 2Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle.

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          Author and article information

          Journal
          Journal ID (nlm-ta): Acta Crystallogr Sect E Struct Rep Online
          Journal ID (publisher-id): Acta Cryst. E
          Title: Acta Crystallographica Section E: Structure Reports Online
          Publisher: International Union of Crystallography
          ISSN (Electronic): 1600-5368
          Publication date Collection: 01 October 2008
          Publication date (Electronic): 06 September 2008
          Publication date PMC-release: 06 September 2008
          Volume: 64
          Issue: Pt 10 ( publisher-idID: e081000 )
          Page: m1252
          Affiliations
          [a ]Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa
          [b ]Department of Chemistry and Biochemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg 2006, South Africa
          Author notes
          Correspondence e-mail: ce@ 123456sun.ac.za
          [‡]

          Currently at Sasol Technology, PO Box 1, Sasolburg 1947, South Africa.

          [§]

          Currently at Sasol Polymers, PO Box 72, Modderfontein 1645, South Africa.

          Article
          Publisher ID: om2260 Coden ID: ACSEBH Publisher Item ID: S1600536808028006
          DOI: 10.1107/S1600536808028006
          PMC ID: 2959354
          PubMed ID: 21201008
          SO-VID: d89bac97-f0f9-4bba-80c5-d8645856af8e
          Copyright © © Esterhuysen et al. 2008
          License:

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          Date received : 26 August 2008
          Date accepted : 02 September 2008
          Categories
          Subject: Metal-Organic Papers

          ScienceOpen disciplines: Materials characterization
          Data availability:
          ScienceOpen disciplines: Materials characterization

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