Simultaneous etching and doping of cobalt sulfides–graphene hybrid with NH 3-plasma effectively enhances the oxygen electrocatalytic activity.
Highly efficient electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) have been regarded as the core elements in a wide range of renewable energy technologies. Surface engineering of the electrocatalysts is one of the most popular strategies to improve their catalytic activity. Herein, we, for the first time, designed an advanced bi-functional electrocatalyst for the ORR and OER by simultaneously etching and doping a cobalt sulfides–graphene hybrid with NH 3-plasma. The graphene supported Co 9S 8 nanoparticles were prepared (denoted as Co 9S 8/G) first, followed by the NH 3-plasma treatment, which could not only lead to nitrogen doping into both Co 9S 8 and graphene, but also partially etch the surface of both Co 9S 8 and graphene. The heteroatom doping could efficiently tune the electronic properties of Co 9S 8 and graphene, and the surface etching could expose more active sites for electrocatalysis, which can contribute significantly to the enhanced electrocatalytic performance for ORR and OER. The electrochemical results revealed that the etched and N-doped Co 9S 8/G shows excellent ORR activity, which is close to that of the commercial Pt/C catalyst, and great OER activity. The strategy developed here provides a novel and efficient approach to prepare hybrid bi-functional electrocatalysts for ORR and OER.