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      Progress in the functional modification of graphene/graphene oxide: a review

      review-article
      , , ,
      RSC Advances
      The Royal Society of Chemistry

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          Abstract

          Graphene and graphene oxide have attracted tremendous interest over the past decade due to their unique and excellent electronic, optical, mechanical, and chemical properties. This review focuses on the functional modification of graphene and graphene oxide. First, the basic structure, preparation methods and properties of graphene and graphene oxide are briefly described. Subsequently, the methods for the reduction of graphene oxide are introduced. Next, the functionalization of graphene and graphene oxide is mainly divided into covalent binding modification, non-covalent binding modification and elemental doping. Then, the properties and application prospects of the modified products are summarized. Finally, the current challenges and future research directions are presented in terms of surface functional modification for graphene and graphene oxide.

          Abstract

          Graphene and graphene oxide have attracted tremendous interest over the past decade due to their unique and excellent electronic, optical, mechanical, and chemical properties.

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          Most cited references97

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          Electric Field Effect in Atomically Thin Carbon Films

          We describe monocrystalline graphitic films, which are a few atoms thick but are nonetheless stable under ambient conditions, metallic, and of remarkably high quality. The films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands, and they exhibit a strong ambipolar electric field effect such that electrons and holes in concentrations up to 10 13 per square centimeter and with room-temperature mobilities of ∼10,000 square centimeters per volt-second can be induced by applying gate voltage.
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            Preparation of Graphitic Oxide

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              The rise of graphene.

              Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.
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                Author and article information

                Journal
                RSC Adv
                RSC Adv
                RA
                RSCACL
                RSC Advances
                The Royal Society of Chemistry
                2046-2069
                17 April 2020
                16 April 2020
                17 April 2020
                : 10
                : 26
                : 15328-15345
                Affiliations
                [a] School of Mechanical Engineering, Xihua University 9999 Hongguang Avenue, Pidu District Chengdu City Sichuan Province 611730 P. R. China
                [b] School of Automation Engineering, University of Electronic Science and Technology of China China
                [c] School of Materials Science and Engineering, Southwest Petroleum University China
                [d] Patent Examination Cooperation Sichuan Center of the Patent Office China
                [e] Petrochina Southwest Pipeline Company China
                Author information
                https://orcid.org/0000-0001-5147-7931
                Article
                d0ra01068e
                10.1039/d0ra01068e
                9052494
                35495479
                cb6fa066-58b5-4ef1-860b-f8cf8b74a8d7
                This journal is © The Royal Society of Chemistry
                History
                : 4 February 2020
                : 24 March 2020
                Page count
                Pages: 18
                Funding
                Funded by: Project of Sichuan Provincial Department of Education, doi 10.13039/501100004884;
                Award ID: 15TD0016
                Categories
                Chemistry
                Custom metadata
                Paginated Article

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