Secondary aerosol formation in winter haze over the Beijing-Tianjin-Hebei Region, China

Abstract. To tackle the problem of severe air pollution, China has implemented active clean air policies in recent years. As a consequence, the emissions of major air pollutants have decreased and the air quality has substantially improved. Here, we quantified China's anthropogenic emission trends from 2010 to 2017 and identified the major driving forces of these trends by using a combination of bottom-up emission inventory and index decomposition analysis (IDA) approaches. The relative change rates of China's anthropogenic emissions during 2010–2017 are estimated as follows: −62 % for SO 2 , −17 % for NO x , +11 % for nonmethane volatile organic compounds (NMVOCs), +1 % for NH 3 , −27 % for CO, −38 % for PM 10 , −35 % for PM 2.5 , −27 % for BC, −35 % for OC, and +16 % for CO 2 . The IDA results suggest that emission control measures are the main drivers of this reduction, in which the pollution controls on power plants and industries are the most effective mitigation measures. The emission reduction rates markedly accelerated after the year 2013, confirming the effectiveness of China's Clean Air Action that was implemented since 2013. We estimated that during 2013–2017, China's anthropogenic emissions decreased by 59 % for SO 2 , 21 % for NO x , 23 % for CO, 36 % for PM 10 , 33 % for PM 2.5 , 28 % for BC, and 32 % for OC. NMVOC emissions increased and NH 3 emissions remained stable during 2010–2017, representing the absence of effective mitigation measures for NMVOCs and NH 3 in current policies. The relative contributions of different sectors to emissions have significantly changed after several years' implementation of clean air policies, indicating that it is paramount to introduce new policies to enable further emission reductions in the future.

Significance The high frequency of haze pollution in China has attracted broad attention and triggered, in 2013, the promulgation of the toughest-ever clean air policy in the country. In this study, we quantified the air quality and health benefits from specific clean air actions by combining a chemical transport model with a detailed emission inventory. As tremendous efforts and resources are needed for mitigating emissions from various sources, evaluation of the effectiveness of these measures can provide crucial information for developing air quality policies in China as well as in other developing and highly polluting countries. Based on measure-specific analysis, our results bear out several important implications for designing future clean air policies.

Aerosols are of central importance for atmospheric chemistry and physics, the biosphere, climate, and public health. The airborne solid and liquid particles in the nanometer to micrometer size range influence the energy balance of the Earth, the hydrological cycle, atmospheric circulation, and the abundance of greenhouse and reactive trace gases. Moreover, they play important roles in the reproduction of biological organisms and can cause or enhance diseases. The primary parameters that determine the environmental and health effects of aerosol particles are their concentration, size, structure, and chemical composition. These parameters, however, are spatially and temporally highly variable. The quantification and identification of biological particles and carbonaceous components of fine particulate matter in the air (organic compounds and black or elemental carbon, respectively) represent demanding analytical challenges. This Review outlines the current state of knowledge, major open questions, and research perspectives on the properties and interactions of atmospheric aerosols and their effects on climate and human health.