Viscous fingering instabilities in spontaneously formed blisters of MoS ₂ multilayers†

Abstract

The viscous fingering in the Hele-Shaw cell can be suppressed by replacing the upper-bounding rigid plate with an elastic membrane. Recently, graphene multilayers while polymer-curing-induced blistering showed the dynamical evolution of viscous fingering patterns on a viscoelastic substrate due to their thickness-dependent elasticity. Under certain conditions, the elastic solid-based instability couples with the viscoelastic substrate-based instability. The mechanisms underlying such a coupling in the blisters of 2D materials and the dynamical evolution of the viscous fingering patterns underneath the blisters are yet to be addressed. Herein, we investigate the viscous fingering instabilities in spontaneously formed blisters of MoS ₂ multilayers, and provide thorough analytical and experimental insights for the elucidation of the dynamical evolution of the viscous fingering patterns and the coupled instabilities in the blisters. We also estimate the interfacial adhesion energy of the MoS ₂ flakes over a (poly)vinyl alcohol (PVA) substrate and the confinement pressure inside the MoS ₂ blisters using a conventional blister-test model. It is observed that the presence of instability gives rise to anomalies in the modeling of the blister test. The adhesion mechanical insights would be beneficial for fundamental research as well as practical applications of 2D material blisters in flexible optoelectronics.

Abstract

A schematic representation of PVA-curing-induced blistering of MoS ₂ multilayers with and without the adsorption of tiny ice-water droplets (mist) over the PVA-coated Pyrex substrate prior to the mechanical exfoliation step.