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      A Review of the Applications and Biodegradation of Polyhydroxyalkanoates and Poly(lactic acid) and Its Composites

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          Abstract

          Overconsumption of plastic goods and improper handling of petroleum-derived plastic waste have brought a plethora of negative impacts to the environment, ecosystem and human health due to its recalcitrance to degradation. These drawbacks become the main driving force behind finding biopolymers with the degradable properties. With the advancement in biopolymer research, polyhydroxyalkanoate (PHA) and poly(lacyic acid) (PLA) and its composites have been alluded to as a potential alternative to replace the petrochemical counterpart. This review highlights the current synthesis process and application of PHAs and PLA and its composites for food packaging materials and coatings. These biopolymers can be further ameliorated to enhance their applicability and are discussed by including the current commercially available packaging products. Factors influencing biodegradation are outlined in the latter part of this review. The main aim of this review article is to organize the scattered available information on various aspects of PHAs and PLA, and its composites for packaging application purposes. It is evident from a literature survey of about 140 recently published papers from the past 15 years that PLA and PHA show excellent physical properties as potential food packaging materials.

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          Most cited references143

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          Production, use, and fate of all plastics ever made

          We present the first ever global account of the production, use, and end-of-life fate of all plastics ever made by humankind.
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            A microbial polyhydroxyalkanoates (PHA) based bio- and materials industry.

            Biopolyesters polyhydroxyalkanoates (PHA) produced by many bacteria have been investigated by microbiologists, molecular biologists, biochemists, chemical engineers, chemists, polymer experts and medical researchers. PHA applications as bioplastics, fine chemicals, implant biomaterials, medicines and biofuels have been developed and are covered in this critical review. Companies have been established or involved in PHA related R&D as well as large scale production. Recently, bacterial PHA synthesis has been found to be useful for improving robustness of industrial microorganisms and regulating bacterial metabolism, leading to yield improvement on some fermentation products. In addition, amphiphilic proteins related to PHA synthesis including PhaP, PhaZ or PhaC have been found to be useful for achieving protein purification and even specific drug targeting. It has become clear that PHA and its related technologies are forming an industrial value chain ranging from fermentation, materials, energy to medical fields (142 references).
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              Bio-nanocomposites for food packaging applications

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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Polymers (Basel)
                Polymers (Basel)
                polymers
                Polymers
                MDPI
                2073-4360
                12 May 2021
                May 2021
                : 13
                : 10
                : 1544
                Affiliations
                School of Industrial Technology, Universiti Sains Malaysia, Minden 11800, Malaysia; jety31@ 123456gmail.com (J.Y.B.); lydiamohamad@ 123456student.usm.my (L.M.); pb5178@ 123456gmail.com (Y.S.K.); taygs@ 123456usm.my (G.S.T.)
                Author notes
                [* ]Correspondence: sitibaidurah@ 123456usm.my ; Tel.: +60-4653-6381
                Author information
                https://orcid.org/0000-0003-4362-0587
                https://orcid.org/0000-0002-7352-023X
                https://orcid.org/0000-0003-3210-7470
                Article
                polymers-13-01544
                10.3390/polym13101544
                8150976
                34065779
                c2a9f496-71e7-4867-a31d-4c1d14bd1b2a
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 26 February 2021
                : 15 March 2021
                Categories
                Review

                polyhydroxyalkanoates,poly(lactic acid),pha-based composites,pla-based composites,biodegradation

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