Direct electrospinning of reconstructable PVDF-TrFE nanofibrous mat onto conductive cement nanocomposite for triboelectricity-assisted net zero energy structure

Abstract As an emerging branch of energy conversion technologies, the triboelectric nanogenerator (TENG) pioneers a brand‐new path to effectively harness varieties of mechanical energies for the purpose of powering and/or sensing. Since its invention in 2012, the TENG has experienced a booming and revolutionary development in every respect, ranging from materials synthesis and modification, architecture design to performance optimization, power management, and application exploration. In comparison to the organic solar cell and organic light‐emitting diodes, TENG is a unique technique that opens the venue of using polymer materials (PMs) for harvesting mechanical energy. So far, by virtue of superior charge transfer and capturing capabilities during friction, various kinds of PMs have been developed and used as triboelectric materials in order to achieve high‐performance TENGs. Here, this work focuses on the utilization and development of PMs for the TENGs technology and first gives a summary of main PMs that are frequently adopted in currently reported energy‐harvesting TENGs. Second, several kinds of PMs used lately in a few novel TENGs for special or specific energy‐harvesting circumstances are introduced and highlighted. Finally, the perspectives on and challenges in developing high‐performance PMs toward TENGs technology are conceived and expected to be instructive to future research. Show more

Understanding of the triboelectric charge accumulation from the view of microcapacitor formation plays a critical role in boosting the output performance of the triboelectric nanogenerator (TENG). Here, an electrospun nanofiber-based TENG (EN-TENG) using a poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE)/MXene nanocomposite material with superior dielectric constant and high surface charge density is reported. The influence of dielectric properties on the output performance of the EN-TENG is investigated theoretically and experimentally. The fabricated EN-TENG exhibited a maximum power density of 4.02 W/m2 at a matching external load resistance of 4 MΩ. The PVDF-TrFE/MXene nanocomposite improved the output performance of the EN-TENG fourfold. The EN-TENG successfully powered an electronic stopwatch and thermo-hygrometer by harvesting energy from human finger tapping. Moreover, it was utilized in smart home applications as a self-powered switch for controlling electrical home appliances, including fire alarms, fans, and smart doors. This work presents an effective and innovative approach toward self-powered systems, human-machine interfaces, and smart home applications. Show more