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      A Stress Analysis of Some Fundamental Specimens of Soft-Matter Quasicrystals with Eightfold Symmetry Based on Generalized Dynamics

      1 , 2 , 3 , 3
      Advances in Materials Science and Engineering
      Hindawi Limited

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          Abstract

          This paper reports a stress analysis of some fundamental samples made of soft-matter quasicrystals with 8-fold symmetry based on the generalized dynamics. The most distinction from the hydrodynamics for solid quasicrystals is that the structure of soft matter belongs to a complex liquid, which is an intermediate phase between solid and liquid and behaves natures of both solid and liquid. In addition, the soft-matter quasicrystals possess high symmetry, and the symmetry breaking is of fundamental importance. So the Landau symmetry breaking theory and elementary excitation principle are therefore the paradigm of the study of soft-matter quasicrystals. Soft-matter quasicrystals belong to the complex fluid, in which the fluid phonon elementary excitation is introduced apart from the phonon and phason elementary excitations. With this model and the equation of state, the equations of motion for possible soft-matter quasicrystals of 8-fold symmetry are derived. The initial boundary value problems for the xy plane field are solved by applying the finite difference method, in which the z-direction represents the 8-fold symmetry axis. A complete hydrodynamics analysis is given to quantitatively explore the phonon, phason, and fluid fields as well as their interactions in the physical time-space domain. The analysis shows the governing equations are exact to the prediction of the dynamics of soft-matter quasicrystals. The computational results reveal the gigantic differences of physical properties between solid and soft-matter quasicrystals.

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          Quasicrystalline order in self-assembled binary nanoparticle superlattices.

          The discovery of quasicrystals in 1984 changed our view of ordered solids as periodic structures and introduced new long-range-ordered phases lacking any translational symmetry. Quasicrystals permit symmetry operations forbidden in classical crystallography, for example five-, eight-, ten- and 12-fold rotations, yet have sharp diffraction peaks. Intermetallic compounds have been observed to form both metastable and energetically stabilized quasicrystals; quasicrystalline order has also been reported for the tantalum telluride phase with an approximate Ta(1.6)Te composition. Later, quasicrystals were discovered in soft matter, namely supramolecular structures of organic dendrimers and tri-block copolymers, and micrometre-sized colloidal spheres have been arranged into quasicrystalline arrays by using intense laser beams that create quasi-periodic optical standing-wave patterns. Here we show that colloidal inorganic nanoparticles can self-assemble into binary aperiodic superlattices. We observe formation of assemblies with dodecagonal quasicrystalline order in different binary nanoparticle systems: 13.4-nm Fe(2)O(3) and 5-nm Au nanocrystals, 12.6-nm Fe(3)O(4) and 4.7-nm Au nanocrystals, and 9-nm PbS and 3-nm Pd nanocrystals. Such compositional flexibility indicates that the formation of quasicrystalline nanoparticle assemblies does not require a unique combination of interparticle interactions, but is a general sphere-packing phenomenon governed by the entropy and simple interparticle potentials. We also find that dodecagonal quasicrystalline superlattices can form low-defect interfaces with ordinary crystalline binary superlattices, using fragments of (3(3).4(2)) Archimedean tiling as the 'wetting layer' between the periodic and aperiodic phases.
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            Supramolecular dendritic liquid quasicrystals.

            A large number of synthetic and natural compounds self-organize into bulk phases exhibiting periodicities on the 10(-8)-10(-6) metre scale as a consequence of their molecular shape, degree of amphiphilic character and, often, the presence of additional non-covalent interactions. Such phases are found in lyotropic systems (for example, lipid-water, soap-water), in a range of block copolymers and in thermotropic (solvent-free) liquid crystals. The resulting periodicity can be one-dimensional (lamellar phases), two-dimensional (columnar phases) or three dimensional ('micellar' or 'bicontinuous' phases). All such two- and three-dimensional structures identified to date obey the rules of crystallography and their symmetry can be described, respectively, by one of the 17 plane groups or 230 space groups. The 'micellar' phases have crystallographic counterparts in transition-metal alloys, where just one metal atom is equivalent to a 10(3)-10(4)-atom micelle. However, some metal alloys are known to defy the rules of crystallography and form so-called quasicrystals, which have rotational symmetry other than the allowed two-, three-, four- or six-fold symmetry. Here we show that such quasiperiodic structures can also exist in the scaled-up micellar phases, representing a new mode of organization in soft matter.
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              Hydrodynamics of icosahedral quasicrystals

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                Author and article information

                Journal
                Advances in Materials Science and Engineering
                Advances in Materials Science and Engineering
                Hindawi Limited
                1687-8434
                1687-8442
                May 07 2019
                May 07 2019
                : 2019
                : 1-13
                Affiliations
                [1 ]School of Natural Science, Shuozhou Advanced Normal College, Shuozhou 036002, Shanxi Province, China
                [2 ]School of Science, Hebei Engineering University, Handan 056038, Hebei Province, China
                [3 ]School of Physics, Beijing Institute of Technology, Beijing 100081, China
                Article
                10.1155/2019/8789151
                beec699b-6c77-4507-8019-da6fff720e51
                © 2019

                http://creativecommons.org/licenses/by/4.0/

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