Flexible Organic–Inorganic Halide Perovskite-Based Diffusive Memristor for Artificial Nociceptors

There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

Abstract

<p xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" class="first" dir="auto" id="d1099826e172">With the current evolution in the artificial intelligence technology, more biomimetic functions are essential to execute increasingly complicated tasks and respond to challenging work environments. Therefore, an artificial nociceptor plays a significant role in the advancement of humanoid robots. Organic-inorganic halide perovskites (OHPs) have the potential to mimic the biological neurons due to their inherent ion migration. Herein, a versatile and reliable diffusive memristor built on an OHP is reported as an artificial nociceptor. This OHP diffusive memristor showed threshold switching properties with excellent uniformity, forming-free behavior, a high ION/IOFF ratio (104), and bending endurance over >102 cycles. To emulate the biological nociceptor functionalities, four significant characteristics of the artificial nociceptor, such as threshold, no adaptation, relaxation, and sensitization, are demonstrated. Further, the feasibility of OHP nociceptors in artificial intelligence is being investigated by fabricating a thermoreceptor system. These findings suggest a prospective application of an OHP-based diffusive memristor in the future neuromorphic intelligence platform. </p>

Related collections

Most cited references 60

Record: found
Abstract: found
Article: not found

Solar cells. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals.

Dong-Dong Shi, Valerio Adinolfi, Riccardo Comin … (2015)

The fundamental properties and ultimate performance limits of organolead trihalide MAPbX3 (MA = CH3NH3(+); X = Br(-) or I(-)) perovskites remain obscured by extensive disorder in polycrystalline MAPbX3 films. We report an antisolvent vapor-assisted crystallization approach that enables us to create sizable crack-free MAPbX3 single crystals with volumes exceeding 100 cubic millimeters. These large single crystals enabled a detailed characterization of their optical and charge transport characteristics. We observed exceptionally low trap-state densities on the order of 10(9) to 10(10) per cubic centimeter in MAPbX3 single crystals (comparable to the best photovoltaic-quality silicon) and charge carrier diffusion lengths exceeding 10 micrometers. These results were validated with density functional theory calculations.

0 comments Cited 846 times – based on 0 reviews      Review now

Bookmark

Record: found
Abstract: found
Article: not found

Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties.

Constantinos Stoumpos, Christos Malliakas, Mercouri Kanatzidis (2013)

A broad organic-inorganic series of hybrid metal iodide perovskites with the general formulation AMI3, where A is the methylammonium (CH3NH3(+)) or formamidinium (HC(NH2)2(+)) cation and M is Sn (1 and 2) or Pb (3 and 4) are reported. The compounds have been prepared through a variety of synthetic approaches, and the nature of the resulting materials is discussed in terms of their thermal stability and optical and electronic properties. We find that the chemical and physical properties of these materials strongly depend on the preparation method. Single crystal X-ray diffraction analysis of 1-4 classifies the compounds in the perovskite structural family. Structural phase transitions were observed and investigated by temperature-dependent single crystal X-ray diffraction in the 100-400 K range. The charge transport properties of the materials are discussed in conjunction with diffuse reflectance studies in the mid-IR region that display characteristic absorption features. Temperature-dependent studies show a strong dependence of the resistivity as a function of the crystal structure. Optical absorption measurements indicate that 1-4 behave as direct-gap semiconductors with energy band gaps distributed in the range of 1.25-1.75 eV. The compounds exhibit an intense near-IR photoluminescence (PL) emission in the 700-1000 nm range (1.1-1.7 eV) at room temperature. We show that solid solutions between the Sn and Pb compounds are readily accessible throughout the composition range. The optical properties such as energy band gap, emission intensity, and wavelength can be readily controlled as we show for the isostructural series of solid solutions CH3NH3Sn(1-x)Pb(x)I3 (5). The charge transport type in these materials was characterized by Seebeck coefficient and Hall-effect measurements. The compounds behave as p- or n-type semiconductors depending on the preparation method. The samples with the lowest carrier concentration are prepared from solution and are n-type; p-type samples can be obtained through solid state reactions exposed in air in a controllable manner. In the case of Sn compounds, there is a facile tendency toward oxidation which causes the materials to be doped with Sn(4+) and thus behave as p-type semiconductors displaying metal-like conductivity. The compounds appear to possess very high estimated electron and hole mobilities that exceed 2000 cm(2)/(V s) and 300 cm(2)/(V s), respectively, as shown in the case of CH3NH3SnI3 (1). We also compare the properties of the title hybrid materials with those of the "all-inorganic" CsSnI3 and CsPbI3 prepared using identical synthetic methods.

0 comments Cited 790 times – based on 0 reviews      Review now

Bookmark

Record: found
Abstract: found
Article: not found

Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide.

Namyoung Ahn, Dae-Yong Son, In-Hyuk Jang … (2015)

High efficiency perovskite solar cells were fabricated reproducibly via Lewis base adduct of lead(II) iodide. PbI2 was dissolved in N,N-dimethyformamide with equimolar N,N-dimethyl sulfoxide (DMSO) and CH3NH3I. Stretching vibration of S═O appeared at 1045 cm(-1) for bare DMSO, which was shifted to 1020 and 1015 cm(-1) upon reacting DMSO with PbI2 and PbI2 + CH3NH3I, respectively, indicative of forming the adduct of PbI2·DMSO and CH3NH3I·PbI2·DMSO due to interaction between Lewis base DMSO and/or iodide (I(-)) and Lewis acid PbI2. Spin-coating of a DMF solution containing PbI2, CH3NH3I, and DMSO (1:1:1 mol %) formed a transparent adduct film, which was converted to a dark brown film upon heating at low temperature of 65 °C for 1 min due to removal of the volatile DMSO from the adduct. The adduct-induced CH3NH3PbI3 exhibited high charge extraction characteristics with hole mobility as high as 3.9 × 10(-3) cm(2)/(V s) and slow recombination rate. Average power conversion efficiency (PCE) of 18.3% was achieved from 41 cells and the best PCE of 19.7% was attained via adduct approach.

0 comments Cited 642 times – based on 0 reviews      Review now

Bookmark

All references

Author and article information

Contributors

Harshada Patil: (View ORCID Profile)

Kalyani D. Kadam: (View ORCID Profile)

Shania Rehman: (View ORCID Profile)

Tukaram D. Dongale: (View ORCID Profile)

Muhammad Farooq Khan: (View ORCID Profile)

Deok-kee Kim: (View ORCID Profile)

Journal

Title: ACS Applied Materials & Interfaces

Abbreviated Title: ACS Appl. Mater. Interfaces

Publisher: American Chemical Society (ACS)

ISSN (Print): 1944-8244

ISSN (Electronic): 1944-8252

Publication date Created: March 15 2023

Publication date (Electronic): March 03 2023

Publication date (Print): March 15 2023

Volume: 15

Issue: 10

Pages: 13238-13248

Affiliations

[1 ]Department of Electrical Engineering, Sejong University, 209-Neungdong-ro, Gwangjin-gu, 05006 Seoul, Republic of Korea

[2 ]Department of Convergence Engineering for Intelligent Drone, Sejong University, 05006 Seoul, Republic of Korea

[3 ]Department of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul 05006, Republic of Korea

[4 ]Computational Electronics and Nanoscience Research Laboratory, School of Nanoscience and Biotechnology, Shivaji University, Kolhapur 416004, India

[5 ]School of Electronics Engineering, Chungbuk National University, Cheongju 28644, Republic of Korea

Article

DOI: 10.1021/acsami.2c16481

PubMed ID: 36867070

SO-VID: bd1d6d9b-9f08-47a3-864c-1c1f59d92aaa

License:

https://doi.org/10.15223/policy-029

https://doi.org/10.15223/policy-037

https://doi.org/10.15223/policy-045

History

Data availability:

Comments

Comment on this article

scite_

Cited by 4

See all cited by

- Version 1

Flexible Organic–Inorganic Halide Perovskite-Based Diffusive Memristor for Artificial Nociceptors

Read this article at

Abstract

Related collections

Artificial Intelligence in Medicine

Most cited references 60

Solar cells. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals.

Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties.

Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide.

Author and article information

Contributors

Journal

Affiliations

Article

History

Comments

Comment on this article

Similar content 3,440

Cited by 4